Application of a novel ethylene-vinyl acetate-graft-2,4,6,8-tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane (EVA-g-V4)material for photovoltaic encapsulation film

IF 2.6 4区 化学 Q3 POLYMER SCIENCE Journal of Polymer Research Pub Date : 2024-10-11 DOI:10.1007/s10965-024-04159-1
Lei Yang, Lijing Gao, Ruiping Wei, Rongying Xia, Ziqi Wang, Huijun Liu, Mingzhu Yao, Guanghui Ma, Guomin Xiao
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Abstract

Ethylene-vinyl acetate (EVA)grafted 2,4,6,8-tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane (V4) polymer EVA-g-V4 was prepared by free-radical solution grafting reaction. The results of the purified grafted products by FT-IR, 1H NMR, XRD, TG and DSC show that V4 has been successfully grafted onto the main chain of EVA. The effects of the dosage of V4 and BPO on grafting ratio were studied. When the dosage of V4 was 6.0 wt%, and the dosage of BPO was 0.8 wt%, the grafting ratio was up to 1.4%. The cross-linking behaviour was verified by SEM. Compared with pure EVA film, the peel strength, mechanical properties, volume resistivity and hydrophobicity of EVA-g-V4 film all improved with increasing grafting ratio. This work provides a new option in the field of photovolatic encapsulation materials.

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新型乙烯-醋酸乙烯接枝-2,4,6,8-四乙烯基-2,4,6,8-四甲基环四硅氧烷(EVA-g-V4)材料在光伏封装薄膜中的应用
通过自由基溶液接枝反应制备了乙烯-醋酸乙烯(EVA)接枝 2,4,6,8-四乙烯基-2,4,6,8-四甲基环四硅氧烷(V4)聚合物 EVA-g-V4。通过傅立叶变换红外光谱(FT-IR)、1H NMR、XRD、TG 和 DSC 对纯化的接枝产物进行测定,结果表明 V4 已成功接枝到 EVA 的主链上。研究了 V4 和 BPO 的用量对接枝率的影响。当 V4 的用量为 6.0 wt%,BPO 的用量为 0.8 wt%时,接枝率可达 1.4%。交联行为由扫描电镜验证。与纯 EVA 薄膜相比,EVA-g-V4 薄膜的剥离强度、机械性能、体积电阻率和疏水性都随着接枝率的增加而提高。这项研究为光固化封装材料领域提供了一种新的选择。
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来源期刊
Journal of Polymer Research
Journal of Polymer Research 化学-高分子科学
CiteScore
4.70
自引率
7.10%
发文量
472
审稿时长
3.6 months
期刊介绍: Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including: polymer synthesis; polymer reactions; polymerization kinetics; polymer physics; morphology; structure-property relationships; polymer analysis and characterization; physical and mechanical properties; electrical and optical properties; polymer processing and rheology; application of polymers; supramolecular science of polymers; polymer composites.
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