Rb3SO4F: Refinement of the Crystal Structure and Thermal Behavior

IF 0.6 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS Glass Physics and Chemistry Pub Date : 2024-09-25 DOI:10.1134/S108765962460025X
M. S. Avdontceva, A. A. Zolotarev, S. V. Krivovichev
{"title":"Rb3SO4F: Refinement of the Crystal Structure and Thermal Behavior","authors":"M. S. Avdontceva,&nbsp;A. A. Zolotarev,&nbsp;S. V. Krivovichev","doi":"10.1134/S108765962460025X","DOIUrl":null,"url":null,"abstract":"<p>The crystal structure and thermal behavior of Rb<sub>3</sub>SO<sub>4</sub>F a new compound is studied by in situ single-crystal X-ray diffraction analysis in a wide temperature range. The compound is stable up to a temperature of 377(10)°C and does not undergo phase transitions during heating. Calculation of the coefficients of the thermal expansion tensor showed that the structure expands strongly anisotropically: the maximum thermal expansion is observed in the <i>ab</i> plane, while the minimum is parallel to the [001] direction, which is closely correlated to changes in bond lengths and angles in the anion-centered FRb<sub>6</sub> octahedron.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"50 2","pages":"191 - 195"},"PeriodicalIF":0.6000,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass Physics and Chemistry","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S108765962460025X","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0

Abstract

The crystal structure and thermal behavior of Rb3SO4F a new compound is studied by in situ single-crystal X-ray diffraction analysis in a wide temperature range. The compound is stable up to a temperature of 377(10)°C and does not undergo phase transitions during heating. Calculation of the coefficients of the thermal expansion tensor showed that the structure expands strongly anisotropically: the maximum thermal expansion is observed in the ab plane, while the minimum is parallel to the [001] direction, which is closely correlated to changes in bond lengths and angles in the anion-centered FRb6 octahedron.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Rb3SO4F:晶体结构和热行为的改进
通过原位单晶 X 射线衍射分析,研究了一种新化合物 Rb3SO4F 在宽温度范围内的晶体结构和热行为。该化合物在高达 377(10)℃ 的温度下保持稳定,并且在加热过程中不会发生相变。对热膨胀张量系数的计算表明,该结构具有强烈的各向异性膨胀:ab 平面上的热膨胀最大,而平行于 [001] 方向的热膨胀最小,这与以阴离子为中心的 FRb6 八面体中键长和角度的变化密切相关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Glass Physics and Chemistry
Glass Physics and Chemistry 工程技术-材料科学:硅酸盐
CiteScore
1.20
自引率
14.30%
发文量
46
审稿时长
6-12 weeks
期刊介绍: Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.
期刊最新文献
Aerodynamic Levitation Melt-Quenching Fabricated Tb3+-Doped La2O3–TiO2–Ga2O3–ZrO2 Glass with a High Verdet Constant for Photonic Applications Influence of Synthesis Conditions on the Functional Composition of the Surface of Cesium-Containing Quartzoid Glasses Structural Transformations of High-Purity Xerogel SiO2 in the Temperature Range of 300–1200°C Hydrothermal Synthesis of Cobalt-Containing Potassium Titanate Nanoparticles Cluster Self-Organization of Intermetallic Systems: Precursor Clusters K3, K4, K5, and K6 for the Self-Assembly of Crystal Structures (Ce4Mg7Ge6)2-mS34, (Eu4Li7Bi6)2-mS34, and Li13Ba8GaSb12-mS34
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1