{"title":"Study on the combustion of toluene by acid etching assisted ultrasonic supported low content Pt catalyst","authors":"","doi":"10.1016/j.apcata.2024.119970","DOIUrl":null,"url":null,"abstract":"<div><div>Catalytic combustion technology is an effective method for the treatment of volatile organic compounds (VOCs). However, the catalytic activity of loaded noble metal catalysts is limited by factors such as high noble metal dosage and poor stability. In this study, a method for the preparation of acid etching assisted ultrasonic loaded low-content Pt-cordierite catalysts was proposed. By comparing with the 0.5 % Pt/cordierite catalyst prepared without acid etching, it was found that the catalytic activity of toluene of the 0.5 % Pt/cordierite-HNO<sub>3</sub> catalyst was significantly improved, and the T<sub>90</sub> of toluene combustion was only 201 ℃, which indicated that the acid etching effectively promoted the interfacial bonding between the active component Pt and the carrier. Finally, it was confirmed by XPS that the active component Pt in the 0.5 % Pt/cordierite-HNO<sub>3</sub> catalyst existed in multiple valence states, which effectively promoted the catalytic combustion of toluene.</div></div>","PeriodicalId":243,"journal":{"name":"Applied Catalysis A: General","volume":null,"pages":null},"PeriodicalIF":4.7000,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Catalysis A: General","FirstCategoryId":"1","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0926860X24004150","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Catalytic combustion technology is an effective method for the treatment of volatile organic compounds (VOCs). However, the catalytic activity of loaded noble metal catalysts is limited by factors such as high noble metal dosage and poor stability. In this study, a method for the preparation of acid etching assisted ultrasonic loaded low-content Pt-cordierite catalysts was proposed. By comparing with the 0.5 % Pt/cordierite catalyst prepared without acid etching, it was found that the catalytic activity of toluene of the 0.5 % Pt/cordierite-HNO3 catalyst was significantly improved, and the T90 of toluene combustion was only 201 ℃, which indicated that the acid etching effectively promoted the interfacial bonding between the active component Pt and the carrier. Finally, it was confirmed by XPS that the active component Pt in the 0.5 % Pt/cordierite-HNO3 catalyst existed in multiple valence states, which effectively promoted the catalytic combustion of toluene.
期刊介绍：
Applied Catalysis A: General publishes original papers on all aspects of catalysis of basic and practical interest to chemical scientists in both industrial and academic fields, with an emphasis onnew understanding of catalysts and catalytic reactions, new catalytic materials, new techniques, and new processes, especially those that have potential practical implications.
Papers that report results of a thorough study or optimization of systems or processes that are well understood, widely studied, or minor variations of known ones are discouraged. Authors should include statements in a separate section "Justification for Publication" of how the manuscript fits the scope of the journal in the cover letter to the editors. Submissions without such justification will be rejected without review.
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