Smartphone-based portable sensor with Bi-MOF nanocomposite for Cd (II) in vegetable samples

Abstract

The accumulation of heavy metal cadmium (Cd) in the food chain poses a serious threat to human health, necessitating the development of rapid, on-site, and portable detection methods for Cd (II). Herein, we developed a smartphone-based electrochemical sensor for portable determination of Cd (II) in vegetables using a bismuth metal–organic framework (Bi-MOF) nanocomposite. Prismatic rod-like Bi-MOF was hydrothermally synthesized using trimesic acid as organic ligands, and subsequently, carboxyl-functionalized multi-walled carbon nanotubes (COOH-MWCNTs) were incorporated to form Bi-MOF nanocomposite network. The smartphone-based electrochemical sensor enables rapid, sensitive, and portable detection of Cd (II) in vegetable samples using Bi-MOF/COOH-MWCNTs-modified screen-printed carbon electrodes (SPCE). A comparative analysis of traditional electrochemical sensors coupled with desktop computer for linear voltametric responses for Cd (II) in the range of 0.2–500 ng/mL with a limit of detection (LOD) of 0.07 ng/mL using Bi-MOF/COOH-MWCNTs-modified glassy carbon electrodes (GCE), the portable sensor demonstrated good linear range in 0.7–350 ng/mL with a LOD of 0.22 ng/mL. This work introduces a novel approach for on-site and portable detection of Cd (II) in agricultural products.