{"title":"Application of molybdenum hexacarbonyl in organic synthesis","authors":"Sambasivarao Kotha , Vidyasagar Gaikwad , Usha Nandan Chaurasia","doi":"10.1016/j.tet.2024.134264","DOIUrl":null,"url":null,"abstract":"<div><div>Here, we describe the role of Mo(CO)<sub>6</sub> in various organic transformations such as Pauson-Khand reaction, carbonyl insertion, epoxidation, oxidation, hydrogenation, reduction, [2 + 2+2] cycloaddition, and cyclization sequences. An overview of the reagent's utility and potential is presented in this review, which presents some natural products as well as other relevant compounds. Many reactions and processes are not possible if we use other catalysts. The reactions facilitated by Mo(CO)<sub>6</sub> also improve the outcome positively.</div></div>","PeriodicalId":437,"journal":{"name":"Tetrahedron","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040402024004459","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
Here, we describe the role of Mo(CO)6 in various organic transformations such as Pauson-Khand reaction, carbonyl insertion, epoxidation, oxidation, hydrogenation, reduction, [2 + 2+2] cycloaddition, and cyclization sequences. An overview of the reagent's utility and potential is presented in this review, which presents some natural products as well as other relevant compounds. Many reactions and processes are not possible if we use other catalysts. The reactions facilitated by Mo(CO)6 also improve the outcome positively.
期刊介绍：
Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry.
Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters.
Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.
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