{"title":"Conversion of Carbon Dioxide into Molecular-based Porous Frameworks","authors":"Kentaro Kadota, Satoshi Horike","doi":"10.1021/acs.accounts.4c00519","DOIUrl":null,"url":null,"abstract":"The conversion of carbon dioxide (CO<sub>2</sub>) to value-added functional materials is a major challenge in realizing a carbon-neutral society. Although CO<sub>2</sub> is an attractive renewable carbon resource with high natural abundance, its chemical inertness has made the conversion of CO<sub>2</sub> into materials with the desired structures and functionality difficult. Molecular-based porous materials, such as metal–organic frameworks (MOFs) and covalent–organic frameworks (COFs), are designable porous solids constructed from molecular-based building units. While MOF/COFs attract wide attention as functional porous materials, the synthetic methods to convert CO<sub>2</sub> into MOF/COFs have been unexplored due to the lack of synthetic guidelines for converting CO<sub>2</sub> into molecular-based building units.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.accounts.4c00519","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The conversion of carbon dioxide (CO2) to value-added functional materials is a major challenge in realizing a carbon-neutral society. Although CO2 is an attractive renewable carbon resource with high natural abundance, its chemical inertness has made the conversion of CO2 into materials with the desired structures and functionality difficult. Molecular-based porous materials, such as metal–organic frameworks (MOFs) and covalent–organic frameworks (COFs), are designable porous solids constructed from molecular-based building units. While MOF/COFs attract wide attention as functional porous materials, the synthetic methods to convert CO2 into MOF/COFs have been unexplored due to the lack of synthetic guidelines for converting CO2 into molecular-based building units.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.