{"title":"Inside Cover Picture","authors":"","doi":"10.1002/cjoc.202490222","DOIUrl":null,"url":null,"abstract":"<p>Practical CO<sub>2</sub> and CO electroreduction are often operated at elevated temperatures, yet the correlation between the temperature increase and catalytic activity and selectivity has not been well-defined. This study uncovers that higher temperatures enhance *CO coverages, but in CO<sub>2</sub> reduction, they also promote *CO desorption to vapor-phase CO, lowering C<sub>2</sub>H<sub>4</sub> selectivity. In CO reduction, elevated temperatures facilitate CO diffusion to overcome the unfavorable *CO adsorption thermodynamics, which promotes C—C coupling. More details are discussed in the article by Wang <i>et al</i>. on pages 2705—2711.\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 22","pages":"2686"},"PeriodicalIF":5.5000,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cjoc.202490222","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cjoc.202490222","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
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Abstract
Practical CO2 and CO electroreduction are often operated at elevated temperatures, yet the correlation between the temperature increase and catalytic activity and selectivity has not been well-defined. This study uncovers that higher temperatures enhance *CO coverages, but in CO2 reduction, they also promote *CO desorption to vapor-phase CO, lowering C2H4 selectivity. In CO reduction, elevated temperatures facilitate CO diffusion to overcome the unfavorable *CO adsorption thermodynamics, which promotes C—C coupling. More details are discussed in the article by Wang et al. on pages 2705—2711.
实际的二氧化碳和一氧化碳电还原通常在较高温度下进行，但温度升高与催化活性和选择性之间的相关性尚未明确。本研究发现，温度升高会提高*CO的覆盖率，但在二氧化碳还原中，温度升高也会促进*CO解吸为气相CO，从而降低C2H4的选择性。在一氧化碳还原过程中，温度升高有利于一氧化碳的扩散，克服不利的*CO吸附热力学，从而促进C-C耦合。更多详情请参见 Wang 等人的文章（第 2705-2711 页）。
期刊介绍：
The Chinese Journal of Chemistry is an international forum for peer-reviewed original research results in all fields of chemistry. Founded in 1983 under the name Acta Chimica Sinica English Edition and renamed in 1990 as Chinese Journal of Chemistry, the journal publishes a stimulating mixture of Accounts, Full Papers, Notes and Communications in English.
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