Pore classification method with steady-state diffusion in complex porous media

IF 3.5 3区 工程技术 Q2 ENGINEERING, CHEMICAL AIChE Journal Pub Date : 2024-10-17 DOI:10.1002/aic.18622
Seunggeon Lee, Dongjae Kim, Jaewook Nam
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Abstract

In porous media, the transport and flow through the void phase are influenced by the internal pore network due to its complex morphology. In other words, the contributions of individual pores can vary due to their connectivity within the network and characteristics in physical phenomena. In this study, we propose a pore classification method according to geometries and physical behaviors to understand the role of each pore in microstructure. Our method classifies entire pores into backbone, dead-end, and isolated pore using connectivity analysis and steady-state diffusion. The backbone acts as the main pathway for the transportation process. Therefore, backbone fraction can be utilized as a quantitative indicator of the pore network in microstructure. Furthermore, this approach enables us to explore the relationship between classified pores and microstructural properties through numerical experiment using virtual structures. This method can be used for various porous materials, such as battery electrodes, membranes, and soil.
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复杂多孔介质中稳态扩散的孔隙分类法
在多孔介质中,由于内部孔隙网络形态复杂,其在空隙相中的传输和流动会受到内部孔隙网络的影响。换句话说,单个孔隙的贡献会因孔隙网络内部的连通性和物理现象的特征而有所不同。在本研究中,我们提出了一种根据几何形状和物理行为进行孔隙分类的方法,以了解每个孔隙在微结构中的作用。我们的方法利用连通性分析和稳态扩散将整个孔隙分为骨干孔隙、死角孔隙和孤立孔隙。主干孔隙是传输过程的主要通道。因此,骨干部分可以作为微结构中孔隙网络的定量指标。此外,这种方法还能让我们利用虚拟结构,通过数值实验探索分类孔隙与微结构特性之间的关系。这种方法可用于各种多孔材料,如电池电极、薄膜和土壤。
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来源期刊
AIChE Journal
AIChE Journal 工程技术-工程:化工
CiteScore
7.10
自引率
10.80%
发文量
411
审稿时长
3.6 months
期刊介绍: The AIChE Journal is the premier research monthly in chemical engineering and related fields. This peer-reviewed and broad-based journal reports on the most important and latest technological advances in core areas of chemical engineering as well as in other relevant engineering disciplines. To keep abreast with the progressive outlook of the profession, the Journal has been expanding the scope of its editorial contents to include such fast developing areas as biotechnology, electrochemical engineering, and environmental engineering. The AIChE Journal is indeed the global communications vehicle for the world-renowned researchers to exchange top-notch research findings with one another. Subscribing to the AIChE Journal is like having immediate access to nine topical journals in the field. Articles are categorized according to the following topical areas: Biomolecular Engineering, Bioengineering, Biochemicals, Biofuels, and Food Inorganic Materials: Synthesis and Processing Particle Technology and Fluidization Process Systems Engineering Reaction Engineering, Kinetics and Catalysis Separations: Materials, Devices and Processes Soft Materials: Synthesis, Processing and Products Thermodynamics and Molecular-Scale Phenomena Transport Phenomena and Fluid Mechanics.
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