Mid-gap levels induced near-infrared response and photothermal catalytic degradation of chlortetracycline hydrochloride by (SnFe2)Ox under solar light

Abstract

We present a comprehensive photocurrent characterization to explore the near-infrared (NIR) response and photothermal effects induced by mid-gap levels in (SnFe₂)O_x (SFO) nanoparticles. X-ray photoelectron spectroscopy and diffuse reflectance spectroscopy revealed multiple mid-gap levels due to multivalent Fe ions. The SFO photocatalyst displayed a noticeable temperature rise under NIR irradiation and a considerable photothermal effect across the full solar spectrum during the photocatalytic degradation of chlortetracycline hydrochloride (CTC·HCl). In photothermal catalysis, after 150 min, SFO was able to remove 88% of CTC·HCl (60 mg/L), outperforming photocatalysis (79%) and thermal catalysis (73%). Rapid and slow response processes were observed in the photocurrent characterization under light-emitting diodes of different wavelengths (365–1500 nm), which revealed a clear dependence on the incident wavelength. Furthermore, innovative photocurrent response tests using alternating ultraviolet (UV) and NIR irradiation revealed that, in the presence of mid-gap levels, UV-excited electrons can aid NIR-excited electrons in achieving cascaded electron transitions, enhancing the utilization of NIR-excited electrons. Our findings demonstrate that mid-gap levels effectively improve the utilization of low-energy photons and boost the photocatalytic process through photothermal effects and increased active charge carrier density.