{"title":"Synthesis and structure of chlororuthenacyclopentatriene†","authors":"Zhenwei Chu, Zhishun Peng, Xu Cheng, Yuhui Hua, Guomei He, Jiangxi Chen and Guochen Jia","doi":"10.1039/D4QI01833H","DOIUrl":null,"url":null,"abstract":"<p >The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl<small><sub>2</sub></small>(PPh<small><sub>3</sub></small>)<small><sub>3</sub></small> with <em>o</em>-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized using spectroscopic data and X-ray diffraction. In addition, computational studies provided evidence for their aromatic character, making them an important supplement to the rare aromatic ruthenacycle family.</p>","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":" 23","pages":" 8479-8488"},"PeriodicalIF":6.4000,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/qi/d4qi01833h","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized using spectroscopic data and X-ray diffraction. In addition, computational studies provided evidence for their aromatic character, making them an important supplement to the rare aromatic ruthenacycle family.
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