Synthesis of Polyether Block Copolymers from 1,2-Epoxybutane and AEOn and Comparative Study of Physicochemical and Application Properties before and after the Synthesis.

Abstract

In this study, the AEO_nBO₂ series of block polyoxybutenol ethers was synthesized by combining the AEO series of polyoxyethylene and preparing 1,2-epoxybutane (BO) block polyether using a semicontinuous method. The synthesis was performed by HPLC, MALDI-TOF-MS, FT-IR, and ¹H NMR for structural analysis. The interaction parameters and surface tension of the systems before and after synthesis were studied using surface tension meter. The diffusion process of the systems before and after synthesis was studied using a KRÜSS bubble pressure tensiometer. The surfactant properties of AEO_n and AEO_nBO₂ were evaluated by static and dynamic surface tension measurements. Each system formed a saturated adsorption layer in a water solution. The critical micelle concentration decreased dramatically after the introduction of BO groups, and the diffusion-adsorption process was consistent with the kinetic mechanism of hybrid diffusion. The microscopic self-assembled aggregate micellar behavior of all the systems was investigated using DLS, TEM, and SEM. The micellization process in all systems was spontaneous and enthalpy-driven, forming spherical aggregates, with the BO block reducing the aggregate diameter of the feedstock from 220.06 nm to about one-third of 80.02 nm. In addition, the dynamic contact angle, application, and physicochemical properties such as foaming and foam stabilization of each system were investigated. The contact angle was reduced from 70 to 50° at 120 s of stabilization, with a foam volume of 80 mL in all systems at 200 s. However, the AEO_nBO₂ showed accelerated foam decay at 500 s, with an increase in the contact angle from 70 to 50° at 200 s, but the AEO_nBO₂ showed accelerated foam decay at 500 s, with a decrease in the contact angle from 70 to 50° at 120 s stabilization. At 200 s, the foam volume of all systems was 80 mL, but AEO_nBO₂ showed an accelerated foam decay process, which shows that the BO group can accelerate the foam decay, and the comparative results show that the BO group can also optimize other application properties and physicochemical properties.