Metal-oxide nanocatalysts for spontaneous sequestration of endocrine-disrupting compounds from wastewater.

Abayomi Bamisaye, Shakirudeen Modupe Abati, Ayodeji Rapheal Ige, Nelson Oshogwue Etafo, Yakubu Adekunle Alli, Muyideen Olaitan Bamidele, Omolabake Abiodun Okon-Akan, Kayode Adesina Adegoke, Olajumoke T Abiola-Kuforiji, Mopelola Abidemi Idowu, Olugbenga Solomon Bello
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Abstract

The quest for a good life, urbanization, and industrialization have led to the widespread distribution of endocrine-disrupting chemicals (EDCs) in water bodies through anthropogenic activities. This poses an imminent threat to both human and environmental health. In recent years, the utilization of advance materials for the removal of EDCs from wastewater has attracted a lot of attention. Metal-oxide nanocatalysts have emerged as promising candidates due to their high surface area, reactivity, and tunable properties, as well as enhanced surface properties such as mesoporous structures and hierarchical morphologies that allow for increased adsorption capacity, improved photocatalytic activity, and enhanced selectivity towards specific EDCs. As a result, they have shown extraordinary efficacy in removing a wide range of EDCs from aqueous solutions, including pharmaceuticals, agrochemicals, personal care items, and industrial chemicals. This study give insight into the unique physicochemical characteristics of metal-oxide nanocatalysts to effectively and efficiently remove harmful EDCs from wastewater. It also discussed the advances in the synthesis, and properties of metal-oxide nanocatalysts, and insight into understanding the fundamental mechanisms underlying the adsorption and degradation of EDCs on metal-oxide nanocatalysts using advanced characterization techniques such as spectroscopic analysis and electron microscopy. The findings of the study present metal-oxide nanocatalysts as a good candidate for the spontaneous sequestration of EDCs from wastewater is an intriguing approach to mitigating water pollution and safeguarding public health and the environment.

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用于自发封存废水中干扰内分泌的化合物的金属氧化物纳米催化剂。
对美好生活的追求、城市化和工业化导致干扰内分泌的化学物质(EDCs)通过人为活动在水体中广泛传播。这对人类和环境健康都构成了迫在眉睫的威胁。近年来,利用先进材料去除废水中的 EDCs 引起了广泛关注。金属氧化物纳米催化剂具有高表面积、高反应活性、可调特性,以及介孔结构和分层形态等增强表面特性,可提高吸附能力、光催化活性和对特定 EDC 的选择性。因此,它们在从水溶液(包括药品、农用化学品、个人护理用品和工业化学品)中去除各种 EDC 方面显示出非凡的功效。本研究深入探讨了金属氧化物纳米催化剂的独特物理化学特性,以有效、高效地去除废水中的有害内分泌干扰化学物质(EDCs)。研究重点是金属氧化物纳米催化剂的合成和性能方面的进展,以及利用光谱分析和电子显微镜等先进表征技术深入了解金属氧化物纳米催化剂吸附和降解 EDCs 的基本机制。研究结果表明,金属氧化物纳米催化剂是自发封存废水中 EDCs 的理想候选材料,是减轻水污染、保护公众健康和环境的一种令人感兴趣的方法。
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