Ion crystal size and structure in Paul traps.

IF 1.1 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL European Journal of Mass Spectrometry Pub Date : 2024-10-01 Epub Date: 2024-10-25 DOI:10.1177/14690667241288376
Appala Naidu Kotana, Atanu K Mohanty
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Abstract

This article presents a relationship between the size of an ion crystal in a Paul trap and the radio frequency potential applied on the central ring electrode. Using a simple and elegant derivation it has been shown that the distance of an ion in the crystal from the trap center is proportional to -2/3 power of the applied radio frequency voltage. The validity of this power law has been demonstrated on ion crystals having up to 13 ions. A spring-mass model has been presented to predict structure of ion crystals in Paul traps operating in the Dehmelt regime. Structures are obtained by minimizing the total potential energy stored in an ion ensemble. The total potential energy is taken to be the sum of the electrostatic potential due to ion-ion interaction and the potential energy stored in the springs. Structures of crystals having up to 13 ions predicted by our model have been verified by comparing them with results obtained by direct numerical simulations.

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保罗陷阱中的离子晶体尺寸和结构。
本文介绍了保罗阱中离子晶体的大小与施加在中心环电极上的射频电势之间的关系。通过简单而优雅的推导,我们发现晶体中的离子距离阱中心的距离与外加射频电压的-2/3次方成正比。这一幂律的有效性已在多达 13 个离子的离子晶体上得到证实。我们提出了一个弹簧质量模型,用于预测在德梅尔特机制下工作的保罗阱中离子晶体的结构。结构是通过最小化存储在离子群中的总势能而获得的。总势能是离子-离子相互作用产生的静电势能与存储在弹簧中的势能之和。通过将我们的模型预测的多达 13 个离子的晶体结构与直接数值模拟得到的结果进行比较,验证了我们的模型。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
2.40
自引率
7.70%
发文量
16
审稿时长
>12 weeks
期刊介绍: JMS - European Journal of Mass Spectrometry, is a peer-reviewed journal, devoted to the publication of innovative research in mass spectrometry. Articles in the journal come from proteomics, metabolomics, petroleomics and other areas developing under the umbrella of the “omic revolution”.
期刊最新文献
Clustering of biphenyl oxamide ions by chiral recognition. Analysis of dimer and trimer complexes of the non-amyloidogenic rat islet amyloid polypeptide 21-37 by electrospray ionization-tandem mass spectrometry. Exploring the versatility of mass spectrometry: Applications across diverse scientific disciplines. Bioanalytical method development and validation of docetaxel and carvacrol in mice plasma using LC-QqQ-MS/MS. Ion crystal size and structure in Paul traps.
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