Biomass-Derived Spherical Carbon Materials for Efficient Electromagnetic Wave Absorption

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-09-27 DOI:10.1021/acsaelm.4c0147510.1021/acsaelm.4c01475
Chengxu Lu, Jianqiao Zhao, Zhaojun An and Guoli Tu*, 
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Abstract

Biomass-derived carbon materials are hot in electromagnetic wave (EMW) absorption due to their wide sources, low cost, and unique structures. Yet, obtaining high-performance EMW absorbers from pure biomass via simple methods is challenging. In this work, a watermelon-derived spherical carbon material (SC-X) with a particle size distribution ranging from 2 to 10 μm was successfully synthesized using a combination of hydrothermal and carbonization methods. By increasing the carbonization temperature, the number of carbon defects in SC-X can be effectively increased, and the polarization loss capacity can be improved, achieving excellent EMW attenuation and impedance matching. The SC-4 carbonized at 900 °C achieved a minimum reflection loss value of −58.7 dB at 12.5 GHz frequency, with an effective absorption bandwidth of 3.5 GHz covering 10.8–14.3 GHz, and the corresponding thickness was only 1.7 mm. This work provides an effective strategy for the large-scale preparation of low-cost and high-performance EMW-absorbing materials derived from biomass.

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用于高效吸收电磁波的生物质球形碳材料
源于生物质的碳材料因其来源广泛、成本低廉、结构独特而成为电磁波(EMW)吸收领域的热门材料。然而,通过简单的方法从纯生物质中获得高性能的电磁波吸收器是一项挑战。在这项工作中,采用水热法和碳化法相结合的方法,成功合成了一种西瓜衍生球形碳材料(SC-X),其粒径分布范围为 2 至 10 μm。通过提高碳化温度,可以有效增加 SC-X 中碳缺陷的数量,提高极化损耗能力,实现优异的电磁波衰减和阻抗匹配。碳化温度为 900 ℃ 的 SC-4 在 12.5 GHz 频率下的最小反射损耗值为 -58.7 dB,有效吸收带宽为 3.5 GHz,覆盖 10.8-14.3 GHz,相应厚度仅为 1.7 mm。这项工作为大规模制备低成本、高性能的生物质电磁波吸收材料提供了有效策略。
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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