Design of hybrid Bi-Zr Perovskite polymer nanocomposites for multifunctional high-performance electrochemical and photonic applications

IF 2.6 4区化学 Q3 POLYMER SCIENCE Journal of Polymer Research Pub Date : 2024-10-28 DOI:10.1007/s10965-024-04179-x

Saravanadevi Kannan, Indhumathi Kamaraj, Jessica Fernando, J. Antony Rajam, Santhosh Kamaraj

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Abstract

The innovation of perovskite-structured materials has revealed remarkable features that make them highly suitable for advanced technology applications. Herein, the exploration of the synthesis of Bi-Zr-O perovskite with a blend of polymer nanocomposites, specifically integrating bismuth zirconate combined with conductive copolymers derived from N-methyl pyrrole and o-anisidine. On utilizing the co-precipitation method Bi-Zr-O perovskite structure has aided to form hybrid polymer nanocomposites as poly-N-methyl pyrrole-BiZrO (PNMPy—BiZrO), poly(o-anisidine)-BiZrO (PoA—BiZrO), and poly(N-methyl pyrrole-co–o-anisidine)-BiZr (PNMPy—PoA—BiZrO) were produced via simultaneous chemical oxidative polymerization. A range of characterization techniques were used in this study. X-ray diffraction confirmed that the perovskite structure of BiZrO was preserved in all samples, and Fourier transform infrared spectroscopy showed that the polymers were successfully integrated into the BiZr matrix. The surface morphologies revealed distinct confirmation of the purity and composition of the materials. The highlight of this research are assessment of blend Bi-Zr-O polymer nanocomposites, emphasizing their potential for advanced optoelectronic and electrochemical applications, particularly in flexible displays with improved transparency and UV-shielding for next-generation electronics.

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设计用于多功能高性能电化学和光子应用的混合铋锆过氧化物聚合物纳米复合材料

透辉石结构材料的创新揭示了其显著特点，使其非常适合先进技术应用。本文探讨了用聚合物纳米复合材料混合合成 Bi-Zr-O 包晶石，特别是将锆酸铋与由 N-甲基吡咯和邻甲氧基苯胺衍生的导电共聚物结合在一起。利用共沉淀法，Bi-Zr-O 包晶结构有助于形成混合聚合物纳米复合材料，如通过同时化学氧化聚合法生产的聚 N-甲基吡咯-BiZrO（PNMPy-BiZrO）、聚（邻甲氧基苯胺）-BiZrO（PoA-BiZrO）和聚（N-甲基吡咯-邻甲氧基苯胺）-BiZr（PNMPy-PoA-BiZrO）。本研究采用了一系列表征技术。X 射线衍射证实所有样品都保留了 BiZrO 的包晶结构，傅立叶变换红外光谱显示聚合物已成功融入 BiZr 基体。表面形态显示，材料的纯度和成分得到了明显的证实。这项研究的亮点是对混合铋锌锇聚合物纳米复合材料的评估，强调了它们在先进光电和电化学应用方面的潜力，特别是在柔性显示器方面，为下一代电子产品提供了更好的透明度和紫外线屏蔽。

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来源期刊

Journal of Polymer Research 化学-高分子科学

CiteScore

4.70

自引率

7.10%

发文量

472

审稿时长

3.6 months

期刊介绍： Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including: polymer synthesis; polymer reactions; polymerization kinetics; polymer physics; morphology; structure-property relationships; polymer analysis and characterization; physical and mechanical properties; electrical and optical properties; polymer processing and rheology; application of polymers; supramolecular science of polymers; polymer composites.