Mathias S Neumann, Sofie K Jensen, Rikke Frederiksen, Sissel S Andersen, Kasper M Beck, Jan O Jeppesen
{"title":"Pushing a bistable [2]rotaxane out of equilibrium and isolation of the metastable-state co-conformation.","authors":"Mathias S Neumann, Sofie K Jensen, Rikke Frederiksen, Sissel S Andersen, Kasper M Beck, Jan O Jeppesen","doi":"10.1039/d4ob01419g","DOIUrl":null,"url":null,"abstract":"<p><p>Incorporating a steric barrier between the two stations in a bistable [2]rotaxane based on monopyrrolotetrathiafulvalene and cyclobis(paraquat-<i>p</i>-phenylene) allows the high-energy metastable-state co-conformation to be physically isolated following a single redox cycle, thus making it possible to store energy (4.4 J L<sup>-1</sup>) and to follow its interconversion back to the ground-state co-conformation.</p>","PeriodicalId":2,"journal":{"name":"ACS Applied Bio Materials","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Bio Materials","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4ob01419g","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, BIOMATERIALS","Score":null,"Total":0}
引用次数: 0
Abstract
Incorporating a steric barrier between the two stations in a bistable [2]rotaxane based on monopyrrolotetrathiafulvalene and cyclobis(paraquat-p-phenylene) allows the high-energy metastable-state co-conformation to be physically isolated following a single redox cycle, thus making it possible to store energy (4.4 J L-1) and to follow its interconversion back to the ground-state co-conformation.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
