Synthesis, Microstructure, and Properties of NaNbO3–LiNbO3 LiF-Doped Ceramics

IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Russian Journal of Physical Chemistry A Pub Date : 2024-10-28 DOI:10.1134/S0036024424701747
G. M. Kaleva, E. D. Politova, S. A. Ivanov, A. V. Mosunov, S. Yu. Stefanovich, N. V. Sadovskaya
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Abstract

Single phase ceramic samples of new compositions (1 − x)NaNbO3хLiNbO3 (x = 0; 0.05; 0.10; 0.15), modified with a LiF additive, are prepared through solid state reactions, and their crystal structure, microstructure and dielectric and nonlinear optical properties are studied. A drop from 108.1 to 42.8 nm of the volume-weighted crystallite size distribution function corresponding to coherent scattering regions is observed. A rise in the temperature of phase transitions and a weakening of nonlinear optical properties are revealed as the concentration of Li cations grows.

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掺杂 LiF 的 NaNbO3-LiNbO3 陶瓷的合成、微观结构和性能
通过固态反应制备了新成分 (1 - x)NaNbO3 - хLiNbO3 (x = 0; 0.05; 0.10; 0.15) 的单相陶瓷样品,并对其晶体结构、微观结构、介电和非线性光学特性进行了研究。观察到与相干散射区域相对应的体积加权晶粒尺寸分布函数从 108.1 纳米下降到 42.8 纳米。随着锂阳离子浓度的增加,相变温度升高,非线性光学特性减弱。
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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
376
审稿时长
5.1 months
期刊介绍: Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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