G. M. Kaleva, E. D. Politova, S. A. Ivanov, A. V. Mosunov, S. Yu. Stefanovich, N. V. Sadovskaya
{"title":"Synthesis, Microstructure, and Properties of NaNbO3–LiNbO3 LiF-Doped Ceramics","authors":"G. M. Kaleva, E. D. Politova, S. A. Ivanov, A. V. Mosunov, S. Yu. Stefanovich, N. V. Sadovskaya","doi":"10.1134/S0036024424701747","DOIUrl":null,"url":null,"abstract":"<p>Single phase ceramic samples of new compositions (1 − <i>x</i>)NaNbO<sub>3</sub> – <i>х</i>LiNbO<sub>3</sub> (<i>x</i> = 0; 0.05; 0.10; 0.15), modified with a LiF additive, are prepared through solid state reactions, and their crystal structure, microstructure and dielectric and nonlinear optical properties are studied. A drop from 108.1 to 42.8 nm of the volume-weighted crystallite size distribution function corresponding to coherent scattering regions is observed. A rise in the temperature of phase transitions and a weakening of nonlinear optical properties are revealed as the concentration of Li cations grows.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024424701747","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Single phase ceramic samples of new compositions (1 − x)NaNbO3 – хLiNbO3 (x = 0; 0.05; 0.10; 0.15), modified with a LiF additive, are prepared through solid state reactions, and their crystal structure, microstructure and dielectric and nonlinear optical properties are studied. A drop from 108.1 to 42.8 nm of the volume-weighted crystallite size distribution function corresponding to coherent scattering regions is observed. A rise in the temperature of phase transitions and a weakening of nonlinear optical properties are revealed as the concentration of Li cations grows.
期刊介绍:
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.