Facile fabrication of green and sustainable gelatin-based aerogels for marine oil spill recovery

IF 6.3 2区 工程技术 Q1 ENGINEERING, CHEMICAL Journal of water process engineering Pub Date : 2024-10-22 DOI:10.1016/j.jwpe.2024.106383
Juan Sun , Jing Qu , Shuixiang Xie , Tong Zhao , Fang Liu , Chunshuang Liu
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Abstract

Efficient and rapid cleanup of marine oil spills is crucial for environmental protection and resource recovery. Biomass aerogel has a broad application prospect in oil spill treatment, but is often limited by the complex preparation process and the use of toxic cross-linking agents. In this study, the hydrophobic gelatin-based aerogels (HGAs) were simply prepared for marine oil spill recovery based on self-crosslinking of gelatin, bubbles produced by surfactants and high-speed stirring, and chemical vapor deposition using methyl trichlorosilane (MTCS). The results showed that the HGAs exhibited a three-dimensional porous structure with a water contact angle of 131.6°. Their adsorption capacities for various oils and organic solvents ranged from 60.4 to 146.5 g/g, which was linearly related to the oil density and depended on the number of pores within the material. The oil adsorption by the HGAs reached equilibrium within 30 s, following the pseudo-second-order kinetic model and the HGAs were highly stable in different temperature, pH, and salinity conditions. Simple squeezing can recover 80 % of the spilled oil, and retain 86 % of the initial adsorption capacity after 10 adsorption-squeeze cycles. Additionally, the HGAs had an excellent continuous oil-water separation performance, demonstrating significant potential and practicability in marine oil spill recovery.

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简便制备用于海洋溢油回收的绿色可持续明胶基气凝胶
高效、快速地清理海洋溢油对环境保护和资源回收至关重要。生物质气凝胶在溢油处理方面具有广阔的应用前景,但往往受制于复杂的制备工艺和有毒交联剂的使用。本研究基于明胶的自交联、表面活性剂和高速搅拌产生的气泡以及使用甲基三氯硅烷(MTCS)的化学气相沉积,简单制备了用于海洋溢油回收的疏水明胶基气凝胶(HGAs)。结果表明,HGA 具有三维多孔结构,水接触角为 131.6°。它们对各种油类和有机溶剂的吸附容量介于 60.4 至 146.5 g/g 之间,与油类密度呈线性关系,并取决于材料内部的孔隙数量。HGAs 对油的吸附在 30 秒内达到平衡,遵循伪二阶动力学模型,并且在不同温度、pH 值和盐度条件下高度稳定。简单挤压可回收 80% 的溢出油,在 10 次吸附-挤压循环后可保留 86% 的初始吸附容量。此外,HGAs 还具有优异的连续油水分离性能,这表明其在海洋溢油回收方面具有巨大的潜力和实用性。
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来源期刊
Journal of water process engineering
Journal of water process engineering Biochemistry, Genetics and Molecular Biology-Biotechnology
CiteScore
10.70
自引率
8.60%
发文量
846
审稿时长
24 days
期刊介绍: The Journal of Water Process Engineering aims to publish refereed, high-quality research papers with significant novelty and impact in all areas of the engineering of water and wastewater processing . Papers on advanced and novel treatment processes and technologies are particularly welcome. The Journal considers papers in areas such as nanotechnology and biotechnology applications in water, novel oxidation and separation processes, membrane processes (except those for desalination) , catalytic processes for the removal of water contaminants, sustainable processes, water reuse and recycling, water use and wastewater minimization, integrated/hybrid technology, process modeling of water treatment and novel treatment processes. Submissions on the subject of adsorbents, including standard measurements of adsorption kinetics and equilibrium will only be considered if there is a genuine case for novelty and contribution, for example highly novel, sustainable adsorbents and their use: papers on activated carbon-type materials derived from natural matter, or surfactant-modified clays and related minerals, would not fulfil this criterion. The Journal particularly welcomes contributions involving environmentally, economically and socially sustainable technology for water treatment, including those which are energy-efficient, with minimal or no chemical consumption, and capable of water recycling and reuse that minimizes the direct disposal of wastewater to the aquatic environment. Papers that describe novel ideas for solving issues related to water quality and availability are also welcome, as are those that show the transfer of techniques from other disciplines. The Journal will consider papers dealing with processes for various water matrices including drinking water (except desalination), domestic, urban and industrial wastewaters, in addition to their residues. It is expected that the journal will be of particular relevance to chemical and process engineers working in the field. The Journal welcomes Full Text papers, Short Communications, State-of-the-Art Reviews and Letters to Editors and Case Studies
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