{"title":"Chiral metal complexes: Design strategies for precision in asymmetric C–H activation","authors":"Devesh Chandra , Tammana Sharma , Sarthi , Sachin , Upendra Sharma","doi":"10.1016/j.jcat.2024.115756","DOIUrl":null,"url":null,"abstract":"<div><div>Due to their unique design, <em>chiral metal</em> complexes play an important role in asymmetric synthesis. In this review, we have focused on the design strategy and its applications in asymmetric C–H functionalization. This review provides a comprehensive overview of chronological development and the future perspective of <em>chiral metal</em> complexes. A brief discussion on the relation between the molecular design of transition metal complex and stereo differentiation in products leading to enantiomeric induction is also included.</div></div>","PeriodicalId":346,"journal":{"name":"Journal of Catalysis","volume":"439 ","pages":"Article 115756"},"PeriodicalIF":6.5000,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Catalysis","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S002195172400469X","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Due to their unique design, chiral metal complexes play an important role in asymmetric synthesis. In this review, we have focused on the design strategy and its applications in asymmetric C–H functionalization. This review provides a comprehensive overview of chronological development and the future perspective of chiral metal complexes. A brief discussion on the relation between the molecular design of transition metal complex and stereo differentiation in products leading to enantiomeric induction is also included.
期刊介绍：
The Journal of Catalysis publishes scholarly articles on both heterogeneous and homogeneous catalysis, covering a wide range of chemical transformations. These include various types of catalysis, such as those mediated by photons, plasmons, and electrons. The focus of the studies is to understand the relationship between catalytic function and the underlying chemical properties of surfaces and metal complexes.
The articles in the journal offer innovative concepts and explore the synthesis and kinetics of inorganic solids and homogeneous complexes. Furthermore, they discuss spectroscopic techniques for characterizing catalysts, investigate the interaction of probes and reacting species with catalysts, and employ theoretical methods.
The research presented in the journal should have direct relevance to the field of catalytic processes, addressing either fundamental aspects or applications of catalysis.
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