Enhanced desalination performance of flow capacitive deionization with the addition of conductive polymer in redox couples and activated carbon

Abstract

Freshwater scarcity is a critical global issue and desalination of brackish water and seawater technologies are regarded as effective solution to mitigate the increasing severity of water shortage. Flow-electrode capacitive deionization (FCDI) is an emerging electrochemical desalination technology capable of continuous deionization behavior. However, reducing energy consumption and enhancing desalination rate are now markedly needed for its advancement. Herein, we propose a FCDI system with energy consumption as low as 88.08 kJ mol⁻¹ and a desalting rate of 1.75 μg cm⁻² s⁻¹. This is achieved by using flow electrodes containing 0.03125 wt% conductive polymer, 5 wt% activated carbon/carbon black and 80 mM/80 mM ferricyanide/ferrocyanide at a current density 3 mA cm⁻² (3.36 mA current for a 1.12 cm² active area). We further investigate the effects of polymer content, redox pair content, salt content and current densities on desalination performance. Seawater with a conductivity of 52.78 mS cm⁻¹ was successfully desalinated to 0.50 mS cm⁻¹ in continuous process. This research provides a promising approach to enhance FCDI system by achieving a low energy consumption and high salt removal rate, representing a significant advancement in continuous electrochemical desalination technology.