Ultrahigh strength – ductility in Ti–6Al–4V composites with high-activity graphene-induced in-situ TiC and coherent nanophases

IF 11.6 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Carbon Pub Date : 2025-01-01 Epub Date: 2024-10-24 DOI:10.1016/j.carbon.2024.119760
Chengze Liu , Longlong Dong , Guodong Sun , Wei Zhang , Junjie Xu , Mingjia Li , Yongqing Fu , Yusheng Zhang
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引用次数: 0

Abstract

Achieving ultra-high strength and ductility of titanium alloys possesses great potential for structural applications in the aerospace and military, yet there is a great challenge for breaking the trade-off barrier of these two properties. In this study, large elongation of ∼10 % and ultra-high tensile strengths of 1510 MPa were obtained in a titanium-based composite. We designed this superior composite based on nanoscale coherent αʹʹ precipitation within near-equiaxed β-Ti as well as micro-scale TiC network architectures along grain boundaries. These in-situ formed triangular αʹʹ coherent precipitates and TiC mainly contributed to the strengthening, while the extremely large elongation resulted from coherent β/αʹʹ interfaces and strain-induced coherent αʹʹ nanotwins. We demonstrated that this composite was easily fabricated using a simple powder metallurgy followed by a hot rolling process. This work can contribute to the design of duplex titanium-based composites as well as other structural materials with exceptional mechanical properties for broad applications.

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具有高活性石墨烯诱导原位 TiC 和相干纳米相的 Ti-6Al-4V 复合材料的超高强度 - 延展性
实现钛合金的超高强度和延展性在航空航天和军事领域的结构应用中具有巨大潜力,但要打破这两种性能的权衡障碍仍面临巨大挑战。在这项研究中,钛基复合材料获得了 10 % 的大伸长率和 1510 兆帕的超高拉伸强度。我们设计的这种优异的复合材料是基于近均相β-钛中的纳米级相干αʹʹ沉淀以及沿晶界的微米级 TiC 网络结构。这些原位形成的三角形αʹʹ相干析出物和TiC对强化起了主要作用,而极高的伸长率则来自相干β/αʹʹ界面和应变诱导的相干αʹʹ纳米网。我们证明,这种复合材料很容易通过简单的粉末冶金和热轧工艺制造出来。这项工作有助于设计双相钛基复合材料以及其他具有优异机械性能的结构材料,从而实现广泛的应用。
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来源期刊
Carbon
Carbon 工程技术-材料科学:综合
CiteScore
20.80
自引率
7.30%
发文量
0
审稿时长
23 days
期刊介绍: The journal Carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials. It reports new findings related to the formation, structure, properties, behaviors, and technological applications of carbons. Carbons are a broad class of ordered or disordered solid phases composed primarily of elemental carbon, including but not limited to carbon black, carbon fibers and filaments, carbon nanotubes, diamond and diamond-like carbon, fullerenes, glassy carbon, graphite, graphene, graphene-oxide, porous carbons, pyrolytic carbon, and other sp2 and non-sp2 hybridized carbon systems. Carbon is the companion title to the open access journal Carbon Trends. Relevant application areas for carbon materials include biology and medicine, catalysis, electronic, optoelectronic, spintronic, high-frequency, and photonic devices, energy storage and conversion systems, environmental applications and water treatment, smart materials and systems, and structural and thermal applications.
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