Insights into the development of carbon molecular sieve membranes from polymer blends for gas separation: A review

0 ENERGY & FUELS Gas Science and Engineering Pub Date : 2024-10-18 DOI:10.1016/j.jgsce.2024.205472
Thaís Martins Neves, Liliane Damaris Pollo, Nilson Romeu Marcilio, Isabel Cristina Tessaro
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Abstract

This study analyzes carbon molecular sieve membranes (CMSM) derived from the pyrolysis of polymer blends. While many studies have focused on modifying polymeric precursors to enhance CMSM performance, blending polymers provides a cost-effective method for creating materials with unique characteristics. However, the literature on CMSM derived from polymer blends is limited. This paper offers background information on CMSM structure and examines parameters affecting their gas separation performance, including the properties of polymeric precursors, blend composition, and pyrolysis conditions. Additionally, it provides valuable insights into unexplored blends for CMSM development, as well as methods to improve the miscibility of polymer blends.

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开发用于气体分离的聚合物混合物碳分子筛膜的启示:综述
本研究分析了聚合物混合物热解产生的碳分子筛膜(CMSM)。虽然许多研究都侧重于改性聚合物前体以提高碳分子筛膜的性能,但聚合物混合物为创造具有独特特性的材料提供了一种具有成本效益的方法。然而,有关聚合物共混物衍生的 CMSM 的文献十分有限。本文提供了有关 CMSM 结构的背景信息,并研究了影响其气体分离性能的参数,包括聚合物前体的特性、共混物成分和热解条件。此外,本文还为开发 CMSM 所需的未开发共混物以及改善聚合物共混物混溶性的方法提供了宝贵的见解。
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