Development of the ENIGMA fuel performance code for LWR applications with chromium-coated cladding

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-10-22 DOI:10.1016/j.nucengdes.2024.113656
Glyn Rossiter , Kerr Fitzgerald , Aiden Peakman
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Abstract

Zirconium-alloy cladding with a chromium coating is the most advanced of the near-term concepts amongst Accident Tolerant Fuel (ATF) materials for Light Water Reactor (LWR) applications. The ENIGMA fuel performance code has been updated to model the thermo-mechanical behaviour of such cladding in both normal and off-normal operating conditions. The focus was on accurately simulating the behaviour in Loss Of Coolant Accident (LOCA) conditions to evaluate the increase in coping time during design-basis accidents. New low-temperature and high-temperature models were incorporated for cladding oxidation and hydriding and cladding creep which take into account the impact of the chromium coating on the overall cladding behaviour. Furthermore, the consumption of the chromium coating due to high-temperature diffusion of chromium into the cladding base alloy’s β-Zr phase is simulated. The new models have been validated using measurements on chromium-coated cladding from irradiated rods, high-temperature annealing experiments and semi-integral LOCA tests. The validation showed good agreement between ENIGMA’s predictions and the experimental data; thereby demonstrating the applicability of the new models for simulating the performance of LWR fuel rods with chromium-coated cladding in both normal operation and accident conditions.
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为使用铬涂层包壳的轻水反应堆应用开发 ENIGMA 燃料性能代码
带铬涂层的锆合金包壳是轻水反应堆(LWR)近期应用的事故耐受燃料(ATF)材料中最先进的概念。ENIGMA 燃料性能代码已经更新,以模拟这种包层在正常和非正常运行条件下的热机械性能。重点是精确模拟失去冷却剂事故(LOCA)条件下的行为,以评估在设计基准事故期间应对时间的增加。针对堆芯氧化和水化以及堆芯蠕变,加入了新的低温和高温模型,其中考虑到了铬涂层对堆芯整体行为的影响。此外,还模拟了由于铬向包层基合金的 β-Zr 相高温扩散而导致的铬涂层消耗。通过对辐照棒铬涂层包层的测量、高温退火实验和半整合 LOCA 试验,对新模型进行了验证。验证结果表明,ENIGMA 的预测结果与实验数据非常吻合,从而证明了新模型适用于模拟带铬涂层的低温反应堆燃料棒在正常运行和事故条件下的性能。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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