β-to-β Singly Linked Subphthalocyanine Dimers with Effective π-Conjugation.

IF 4.9 1区化学 Q1 CHEMISTRY, ORGANIC Organic Letters Pub Date : 2024-10-31 DOI:10.1021/acs.orglett.4c03407

Daniel Holgado, Marta Gómez-Gómez, Jorge Labella, Tomás Torres

引用次数: 0

Abstract

In this work, a series of π-conjugated Subphthalocyanine dimers assembled by simple π-bridges were efficiently synthesized through metal-catalyzed reactions. Despite being singly linked, these readily accessible arrays exhibit excellent π-electron communication, significantly perturbing the orbital distribution of conventional SubPcs and inducing notable alterations in their optical properties. The findings presented here demonstrate the potential of SubPcs for constructing curved porphyrin arrays with well-conjugated skeletons and intriguing functionalities.

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具有有效 π 共轭作用的 β 对 β 单链亚酞菁二聚体。

在这项工作中，我们通过金属催化反应，高效合成了一系列由简单的 π 桥组装而成的 π 共轭亚酞菁二聚体。尽管这些二聚体是单链的，但它们的π电子传递性能极佳，极大地扰乱了传统亚酞菁的轨道分布，使它们的光学特性发生了显著的变化。本文的研究结果证明了 SubPcs 在构建具有良好共轭骨架和有趣功能的弯曲卟啉阵列方面的潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.