Degradation mechanism of oil–pressboard insulation by multiphysical field aging characteristics and cellulose crytallinity

IF 4.9 2区 工程技术 Q1 MATERIALS SCIENCE, PAPER & WOOD Cellulose Pub Date : 2024-10-04 DOI:10.1007/s10570-024-06151-w
Guan Wang, Kuo Yan, Zhongyu Zhao, Zihao Li, Hongshun Liu, Qingquan Li
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Abstract

Oil–pressboard insulation in converter transformer is subjected to the combined effects of AC and DC electric fields, high temperature, and mechanical vibration in actual operation, with a serious impact on its deterioration. In this study, comparative tests are performed of coupled electrical–thermal–mechanical aging, and several characteristic parameters that characterize the degree of aging of oil–pressboard are measured. Relationships between aging parameters are established, with the degree of polymerization (DP) of the pressboard being adopted as the criterion to characterize the degree of aging. Scanning electron microscopy and X-ray diffraction are used to investigate the surface morphology and crystal structure of the pressboard at different aging stages. Then, the influences of temperature, electric field and mechanical field on the cracking mechanism of the oil–pressboard insulation in terms of the aging characteristic parameters and the changes in cellulose crystallinity were analyzed. It is finally found that thermal stress is the most important factor involved in insulation pressboard cracking. The addition of electric and mechanical fields will reduce the crystallite size of the cellulose pressboard material, increase the acid value and furfural content of the oil, and increase the rate of decrease in the degree of polymerization of the pressboard. All of which accelerate the aging of the oil–pressboard insulation.

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多物理场老化特性和纤维素结晶度对油压板绝缘材料的降解机理影响
换流变压器中的油压板绝缘在实际运行中会受到交直流电场、高温和机械振动的共同作用,对其老化产生严重影响。本研究进行了电-热-机械耦合老化对比试验,并测量了表征油压板老化程度的几个特征参数。建立了老化参数之间的关系,并将压纸板的聚合度(DP)作为表征老化程度的标准。使用扫描电子显微镜和 X 射线衍射法研究了不同老化阶段压纸板的表面形态和晶体结构。然后,从老化特征参数和纤维素结晶度变化的角度分析了温度、电场和机械场对油压纸板绝缘层开裂机理的影响。最终发现,热应力是绝缘压纸板开裂的最重要因素。电场和机械场的加入会减小纤维素压板材料的结晶尺寸,增加油的酸值和糠醛含量,提高压板聚合度的下降速度。所有这些都会加速油压纸板绝缘层的老化。
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来源期刊
Cellulose
Cellulose 工程技术-材料科学:纺织
CiteScore
10.10
自引率
10.50%
发文量
580
审稿时长
3-8 weeks
期刊介绍: Cellulose is an international journal devoted to the dissemination of research and scientific and technological progress in the field of cellulose and related naturally occurring polymers. The journal is concerned with the pure and applied science of cellulose and related materials, and also with the development of relevant new technologies. This includes the chemistry, biochemistry, physics and materials science of cellulose and its sources, including wood and other biomass resources, and their derivatives. Coverage extends to the conversion of these polymers and resources into manufactured goods, such as pulp, paper, textiles, and manufactured as well natural fibers, and to the chemistry of materials used in their processing. Cellulose publishes review articles, research papers, and technical notes.
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