Enhanced sensitivity and selectivity of ZnSe/PANI nanocomposite for Low-ppm NO2 detection at room temperature gas sensor application

Abstract

The utilization of n-p composite-based gas sensors has garnered substantial interest within the field of gas sensing. This heightened attention can be attributed to the remarkable band alignment of the constituent materials which results in superior charge transfer rate, increased gas interaction sites and reduced optimum operating temperature. In this work, n-ZnSe/p-PANI composites were prepared by simple hydrothermal technique. The obtained X-ray diffraction pattern confirms the phase formation ZnSe, PANI and ZnSe/PANI composites. The pure ZnSe exhibits a sensing performance at a higher operating temperature of 100 °C, whereas ZnSe/PANI composite sample demonstrates an improved sensing response at 30 °C. Notably, the 20 wt.% composite sample (ZnSe–P2) achieved a maximum sensing response of 77 % towards 20 ppm of NO₂ gas molecule. Additionally, the sensor exhibits the response time (T_res) of 112 s and recovery time (T_rec) of 648 s, at an operating temperature of 30 °C. It also shows better stability, reproducibility and specific selectivity towards NO₂ gas molecule. The superior sensing behavior of the ZnSe-P2 sensor can be ascribed to the development of a depletion region in the interface of ZnSe/PANI composites, which improved the charge transfer rate and increased the number of reactive sites. Therefore, the formation of n-p inorganic-organic composite strategy offers an effective approach for detecting NO₂ gas molecules at lower temperature of 30 °C.