Synthesis, characterization and study of Sb(Ⅲ) adsorption from aqueous solution by iron-aluminum pillared attapulgite

Abstract

In this study, a simple, environmentally friendly and inexpensive adsorbent for Sb(III) in aqueous solution was prepared by the copolymerization method using attapulgite as the matrix, FeCl₃ and AlCl₃ as the metal sources. The morphology and structure of iron-aluminum pillared attapulgite were analyzed through various characterization methods. The conditions and influencing factors of iron-aluminum pillared attapulgite preparation and Sb(III) adsorption were studied. The saturated adsorption capacity of Sb(III) could reach 60.44 mg·g⁻¹ for 180 min at pH 7 and 298 K. The adsorption process is conformed to Langmuir isothermal model and pseudo-second-order kinetic model, and the thermodynamic investigation suggested a spontaneous and endothermic adsorption process. It was revealed by X-ray photoelectron spectroscopy analysis and Zeta potential analysis that Sb(III) was first electrostatically adsorbed by the adsorbent, part of Sb(III) was oxidized to Sb(V) by Fe(III) and then antimony was complexed with iron and aluminum hydroxides to form surface complexes. In addition, a small amount of antimony migrated through intra-particle diffusion into the internal micropores and reacted with hydroxyl groups. Most coexisting components under the chosen conditions had no influence on Sb(III) adsorption, and PO₄³⁻, AsO₃³⁻, C₆H₈O₇ and H₂C₂O₄ had a negligible effect. However, the adsorption capacity of over 90 % without interference showed that the material has a strong selectivity for Sb(III) adsorption. The findings of the desorption experiment showed that the adsorption product has a considerable degree of desorption at increased hydrochloric acid concentrations. It may be concluded that the adsorption product is more stable in the overall polluted water environment since the actual acidity of the polluted water environment is significantly lower than the desorption experiment acidity. Overall, iron-aluminum pillared attapulgite has great potential for application in removing Sb(III).