Target Configuration Effect on Microstructures and Properties of Vertically Aligned Nanocomposites

IF 3.4 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Crystal Growth & Design Pub Date : 2024-10-09 DOI:10.1021/acs.cgd.4c00958
Lizabeth Quigley, Jianan Shen, Juanjuan Lu, Claire A. Mihalko, James P. Barnard, Yizhi Zhang, Nirali A. Bhatt, Katrina Evancho, Raktim Sarma, Aleem Siddiqui and Haiyan Wang*, 
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Abstract

Vertically aligned nanocomposites (VANs) are unique thin films with vertical nanostructures embedded in a matrix material, allowing for the integration of two distinct materials. These nanocomposites offer novel combined physical properties, such as nanocomposite-based multiferroics and strongly coupled physical properties, such as magneto-optic coupling. Much work has been conducted in exploring different two-phase combinations and various processing conditions to achieve novel tunable properties that cannot be obtained by any single-phase material alone. In this work, the target configuration effects are explored for the growth of LaFeO3–CoNi2O4 VANs. Both mixed and pie-shaped targets are utilized to compare the target configuration effects on the phase separation, morphology tuning, and their resulting physical properties, including optical and magnetic properties. This work suggests that the target configuration is another important parameter for achieving the desired VAN morphology and can be used to design different two-phase VANs with tailorable properties.

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靶配置对垂直排列纳米复合材料微结构和性能的影响
垂直排列纳米复合材料(VANs)是一种独特的薄膜,其垂直纳米结构嵌入基体材料中,从而实现了两种不同材料的整合。这些纳米复合材料具有新颖的组合物理性质,如基于纳米复合材料的多铁性和强耦合物理性质,如磁光耦合。为了获得任何单相材料都无法实现的新型可调特性,人们在探索不同的两相组合和各种加工条件方面做了大量工作。在这项工作中,我们探讨了生长 LaFeO3-CoNi2O4 VAN 时靶材配置的影响。我们利用混合靶和饼状靶,比较了靶配置对相分离、形貌调整及其产生的物理性质(包括光学和磁学性质)的影响。这项研究表明,靶材构型是实现理想的 VAN 形貌的另一个重要参数,可用于设计具有可定制特性的不同两相 VAN。
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来源期刊
Crystal Growth & Design
Crystal Growth & Design 化学-材料科学:综合
CiteScore
6.30
自引率
10.50%
发文量
650
审稿时长
1.9 months
期刊介绍: The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials. Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.
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