{"title":"Microfluidic Synthesis of Defective and Hierarchical Pore Zr Metal–Organic Framework Materials and CO2 Adsorption Performance Study","authors":"Xuehui Ge, Zihan Liu, Nanjie Wei, Xiaocheng Lin* and Cejun Hu*, ","doi":"10.1021/acs.cgd.4c01106","DOIUrl":null,"url":null,"abstract":"<p >Microfluidic synthesis has emerged as a promising method for synthesizing metal–organic frameworks (MOFs). It overcomes the limitations of the traditional solvothermal method to regulate the structure and function of the MOFs. This study synthesized various MOFs with different structures and functions by controlling the reaction time and the ratio of metal ions to organic ligands through microfluidics and investigated their CO<sub>2</sub> adsorption properties. The results showed that the microfluidic synthesized defective and hierarchical pore MOF-808 improved the adsorption performance of CO<sub>2</sub> by nearly 110% and 30%, respectively, compared with solvothermal synthesized MOF-808.</p>","PeriodicalId":34,"journal":{"name":"Crystal Growth & Design","volume":"24 21","pages":"9084–9096 9084–9096"},"PeriodicalIF":3.4000,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Growth & Design","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.cgd.4c01106","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Microfluidic synthesis has emerged as a promising method for synthesizing metal–organic frameworks (MOFs). It overcomes the limitations of the traditional solvothermal method to regulate the structure and function of the MOFs. This study synthesized various MOFs with different structures and functions by controlling the reaction time and the ratio of metal ions to organic ligands through microfluidics and investigated their CO2 adsorption properties. The results showed that the microfluidic synthesized defective and hierarchical pore MOF-808 improved the adsorption performance of CO2 by nearly 110% and 30%, respectively, compared with solvothermal synthesized MOF-808.
期刊介绍：
The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials.
Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
