Shi Zhang, Yanping Zhao, Ying Wang, Guojian Chen, Qingfu Zhang, Yanli Gai* and Kecai Xiong*,
{"title":"A Viologen-Based MOF: Photoresponsive Discoloration Property and Selective Fluorescence Detection of Nitrofurans and Lysine","authors":"Shi Zhang, Yanping Zhao, Ying Wang, Guojian Chen, Qingfu Zhang, Yanli Gai* and Kecai Xiong*, ","doi":"10.1021/acs.cgd.4c0122610.1021/acs.cgd.4c01226","DOIUrl":null,"url":null,"abstract":"<p >A metal–organic framework featuring a 3-fold interpenetrating diamondoid structure has been constructed utilizing a viologen derivative, 1,1′-bis(4-carboxyphenyl)-(4,4′-bipyridinium) dichloride. This compound demonstrates good performance as a multifunctional colorimetric and fluorescence sensor. The incorporation of viologen imparts the compound with a visible photoresponsive discoloration property. Furthermore, this compound exhibits the ability to detect nitrofurans and lysine through fluorescence turn-off and turn-on mechanisms, respectively.</p>","PeriodicalId":3,"journal":{"name":"ACS Applied Electronic Materials","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Electronic Materials","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.cgd.4c01226","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
A metal–organic framework featuring a 3-fold interpenetrating diamondoid structure has been constructed utilizing a viologen derivative, 1,1′-bis(4-carboxyphenyl)-(4,4′-bipyridinium) dichloride. This compound demonstrates good performance as a multifunctional colorimetric and fluorescence sensor. The incorporation of viologen imparts the compound with a visible photoresponsive discoloration property. Furthermore, this compound exhibits the ability to detect nitrofurans and lysine through fluorescence turn-off and turn-on mechanisms, respectively.