Alexander D. Roth, Zhazira Koldasbay, Brett H. Ford, Khaidar Kairbek, Heejoon Ahn, Tarini S. Hardikar, Katherine M. Lane, Sarah M. Haynes, Dasan M. Thamattoor
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引用次数: 0
Abstract
Various 9,10-cyclopropanated phenanthrenes have been shown previously to be viable photochemical precursors to many different types of carbenes. There is also one known example in the literature of a related approach used to generate diphenylketene from a phenanthrene-derived cyclobutanone in a laser flash photolysis study. In an effort to broaden the scope of this promising yet under-utilized method of ketene generation, the synthesis and characterization of several phenanthrene-based cyclobutanones, and their subsequent photolysis to produce a variety of ketenes, are presented in this report. The ketenes are produced, along with phenanthrene, by a formal 2 + 2 cyclo-reversion of the cyclobutanone moiety and have been intercepted by benzyl alcohol and benzyl amine to form the corresponding benzyl esters and amides respectively.
期刊介绍：
Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry.
Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters.
Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.
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