{"title":"Assessment of cerium adsorption potential of phosphoric acid activated biochar in aqueous system: Modelling and mechanistic insights","authors":"Jeevanantham Sathasivam , Prasanna Venkatesh Rajaraman , Selvaraju Narayanasamy","doi":"10.1016/j.envres.2024.120301","DOIUrl":null,"url":null,"abstract":"<div><div>Cerium pollution in waterbodies by improper industrial waste disposal is a major concern due to its detrimental impacts on the environment. Therefore, treatment of cerium-contaminated water is inevitable. Hence, this study is focused on the remediation of cerium pollution using phosphoric acid-activated biochar (PPMB) as an adsorbent, synthesized upon pyrolytic activation of palmyra palm male flower-based pristine biochar (PMFB) with H<sub>3</sub>PO<sub>4</sub> at 500 °C. The physico-chemical surface properties of PMFB and PPMB were evaluated through various microscopic and spectroscopic analyses. The key parameters such as biochar dosage, pH, temperature, contact time and initial cerium concentration were optimized as 0.5 g/L, 5.0, 303 K, 180 min and 50 mg/L respectively via batch adsorption. Pseudo-second order kinetic and Toth isotherm are the best-fitted models. The thermodynamic parameters including ΔG<sup>◦</sup> (−30.4707 ± 0.7618 kJ/mol at 303 K), ΔH<sup>◦</sup> (16.1499 ± 0.78 kJ/mol), and ΔS<sup>◦</sup> (153.617 ± 3.8404 J/mol/K) conveying that cerium adsorption onto PPMB was spontaneous, endothermic, and highly disordered at PPMB-bulk adsorption medium interface. Precipitation, electrostatic attraction, and surface complexation are predicted to be the predominant mechanisms for the chosen PPMB-cerium adsorption system. Moreover, cerium phytotoxicity on <em>Vigna radiata</em> explains the real-time applicability and feasibility of cerium adsorption using PPMB. Thus, the key findings of this study specified that the higher adsorption capacity of PPMB (141.3484 ± 6.9856 mg/g) contributed by the incorporated phosphate groups, predominant mesoporosity, SSA<sub>BET</sub> of 230.559 m<sup>2</sup>/g and anionic surface at a wider pH range (pH>3.08) make PPMB as efficient, economically feasible and environmentally friendly adsorbent for cerium adsorption in aqueous system.</div></div>","PeriodicalId":312,"journal":{"name":"Environmental Research","volume":"264 ","pages":"Article 120301"},"PeriodicalIF":7.7000,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Research","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0013935124022084","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
Cerium pollution in waterbodies by improper industrial waste disposal is a major concern due to its detrimental impacts on the environment. Therefore, treatment of cerium-contaminated water is inevitable. Hence, this study is focused on the remediation of cerium pollution using phosphoric acid-activated biochar (PPMB) as an adsorbent, synthesized upon pyrolytic activation of palmyra palm male flower-based pristine biochar (PMFB) with H3PO4 at 500 °C. The physico-chemical surface properties of PMFB and PPMB were evaluated through various microscopic and spectroscopic analyses. The key parameters such as biochar dosage, pH, temperature, contact time and initial cerium concentration were optimized as 0.5 g/L, 5.0, 303 K, 180 min and 50 mg/L respectively via batch adsorption. Pseudo-second order kinetic and Toth isotherm are the best-fitted models. The thermodynamic parameters including ΔG◦ (−30.4707 ± 0.7618 kJ/mol at 303 K), ΔH◦ (16.1499 ± 0.78 kJ/mol), and ΔS◦ (153.617 ± 3.8404 J/mol/K) conveying that cerium adsorption onto PPMB was spontaneous, endothermic, and highly disordered at PPMB-bulk adsorption medium interface. Precipitation, electrostatic attraction, and surface complexation are predicted to be the predominant mechanisms for the chosen PPMB-cerium adsorption system. Moreover, cerium phytotoxicity on Vigna radiata explains the real-time applicability and feasibility of cerium adsorption using PPMB. Thus, the key findings of this study specified that the higher adsorption capacity of PPMB (141.3484 ± 6.9856 mg/g) contributed by the incorporated phosphate groups, predominant mesoporosity, SSABET of 230.559 m2/g and anionic surface at a wider pH range (pH>3.08) make PPMB as efficient, economically feasible and environmentally friendly adsorbent for cerium adsorption in aqueous system.
期刊介绍:
The Environmental Research journal presents a broad range of interdisciplinary research, focused on addressing worldwide environmental concerns and featuring innovative findings. Our publication strives to explore relevant anthropogenic issues across various environmental sectors, showcasing practical applications in real-life settings.