Effects of the combined use of lanthanum carbonate and activated carbon capping materials on phosphorus and dissolved organic matter in lake sediments

Abstract

Lanthanum carbonate (LC) represents a novel material for the immobilization of internal phosphorus (P) in sediments. Activated carbon (AC) is a traditional adsorbent that has been employed in the remediation of sediments on a wide scale. The objective of this study is to examine the mechanisms and effects of the combined use of LC and AC capping materials on the immobilization of P and dissolved organic matter (DOM) in sediments, through a 90-day incubation experiment. The results of isotherm experiments showed that the adsorption mechanism of P on LC and AC was mainly chemisorption. The XPS analyses showed the adsorption mechanism of P on LC was mainly ligand exchange and inner-sphere complexation; while the adsorption mechanism of P on AC was mainly ligand exchange and electrostatic adsorption. The results demonstrated that the concentrations of soluble reactive phosphorus (SRP) and DOM in the 0 to −100 mm sediment layer were reduced by 69.79% and 33.93%, respectively, in comparison to the control group with the LC + AC group. Moreover, the HCl-P and Res-P (stable P) in the 0–5 cm sediment layer were increased by 50.07% and 21.04%, respectively, in the LC + AC group. This indicates that the combined application of LC and AC has the potential to reduce the risk of P release. Furthermore, the formation of Fe(III)/Mn(IV) oxyhydroxides by LC + AC treatment resulted in an increased adsorption of SRP and DOM. Moreover, the effect of LC + AC capping on microbial community was smaller than that of LC/AC capping alone. The findings of this study indicated that the combined use of LC and AC represents a novel approach to the effective treatment of internal P and DOM in eutrophic lake sediments.