{"title":"Alternating Radical Copolymerization of α-Styrylboronic Acid Pinacol Ester with Electron-Deficient Olefins","authors":"Yiyang Xiao, Zepeng Zhang, Yan Xu, Jianbo Wang","doi":"10.1039/d4py00976b","DOIUrl":null,"url":null,"abstract":"Here, α-styryl boronic acid pinacol ester (StBpin) has been found to undergo alternating radical copolymerization with electron-deficient olefin comonomers, including n-butyl acrylate, N,N-dimethylacrylamide, acrylonitrile, and N-ethylmaleimide. Compared with styrene, which also copolymerizes with these electron-deficient olefins in alternative manner, StBpin resulted in the formation of copolymers with higher alternating selectivity, but lower yields and low molecular weights due to its diminished reactivity.","PeriodicalId":100,"journal":{"name":"Polymer Chemistry","volume":"13 1","pages":""},"PeriodicalIF":4.1000,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4py00976b","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Here, α-styryl boronic acid pinacol ester (StBpin) has been found to undergo alternating radical copolymerization with electron-deficient olefin comonomers, including n-butyl acrylate, N,N-dimethylacrylamide, acrylonitrile, and N-ethylmaleimide. Compared with styrene, which also copolymerizes with these electron-deficient olefins in alternative manner, StBpin resulted in the formation of copolymers with higher alternating selectivity, but lower yields and low molecular weights due to its diminished reactivity.
期刊介绍:
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.