A Pathway Analysis Framework for Evaluating the Economic and Environmental Viability of Biomass-Based Plastic Production

IF 7.1 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY ACS Sustainable Chemistry & Engineering Pub Date : 2024-11-07 DOI:10.1021/acssuschemeng.4c06551
Bo-Xun Wang, Jiqing Zhuang, Victor M. Zavala
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Abstract

Plastic production from fossil feedstocks (e.g., naphtha, coal, and natural gas) is not sustainable and causes known environmental impacts such as global warming. A possible solution is to shift production pathways to use biomass, which is a sustainable feedstock that can sequester atmospheric carbon dioxide. This study presents an optimization-based pathway analysis framework for evaluating the carbon footprints of the production of mainstream plastics from biomass and fossil feedstocks. We use the modeling framework to quickly navigate complex interdependencies that exist between the production pathways of different plastics and to determine pathways of minimum production cost under a range of carbon pricing scenarios. The framework interprets carbon prices as an exogenous taxation scheme or an endogenous negative value perceived by producers. The proposed approach reveals the biomass feedstock quantities needed to displace fossil counterparts and the plastics and technologies that should be prioritized. The framework can also be used for evaluating system-wide trade-offs between production costs and carbon footprints that arise from pathway interdependencies. We also evaluate hidden environmental impacts associated with the large-scale use of biomass as a feedstock, such as land use and water eutrophication that results from a significant increase in fertilizer use. Therefore, it is important to highlight that there are trade-offs between decarbonization and other environmental issues. The proposed framework provides an integrative platform for basic techno-economic and life-cycle data that can be used for analyzing diverse scenarios and determining necessary technology targets (e.g., yields, footprints, and costs) to achieve required levels of decarbonization.

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评估生物质塑料生产的经济和环境可行性的途径分析框架
用化石原料(如石脑油、煤和天然气)生产塑料是不可持续的,而且会造成已知的环境影响,如全球变暖。一个可行的解决方案是将生产路径转向使用生物质,因为生物质是一种可持续的原料,能够封存大气中的二氧化碳。本研究提出了一个基于优化的途径分析框架,用于评估利用生物质和化石原料生产主流塑料的碳足迹。我们利用该建模框架快速浏览不同塑料生产路径之间存在的复杂相互依存关系,并确定一系列碳定价情景下生产成本最低的路径。该框架将碳价格解释为外生税收计划或生产者感知到的内生负值。建议的方法揭示了替代化石原料所需的生物质原料数量,以及应优先考虑的塑料和技术。该框架还可用于评估生产成本与碳足迹之间的全系统权衡,这些权衡是由途径的相互依存性引起的。我们还评估了与大规模使用生物质作为原料相关的隐性环境影响,如化肥用量大幅增加导致的土地使用和水体富营养化。因此,必须强调脱碳与其他环境问题之间的权衡。拟议的框架为基本的技术经济和生命周期数据提供了一个综合平台,可用于分析各种方案和确定必要的技术目标(如产量、足迹和成本),以实现所需的脱碳水平。
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来源期刊
ACS Sustainable Chemistry & Engineering
ACS Sustainable Chemistry & Engineering CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL
CiteScore
13.80
自引率
4.80%
发文量
1470
审稿时长
1.7 months
期刊介绍: ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment. The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.
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