Eco-friendly micro-mesoporous carbon from sucrose and sodium metasilicate template for ciprofloxacin adsorption: Effect of molecules self-association over diffusion mechanisms
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引用次数: 0
Abstract
A green synthesis route of ordered mesoporous carbon by nanocasting of sucrose/sodium metasilicate with template removal only by hot water (70 °C) is proposed. The metasilicate-sucrose mesoporous carbon (MSMC) was characterized by structural, textural, surface chemistry properties and their effect on ciprofloxacin (CIP) adsorption. Phenomenological modeling was applied, including two surface-reaction models: adsorption on adsorbent sites (AAS) and on heterogeneous surface (AHS), and two mass transfer models: external film (EFD) and intraparticle homogeneous (IHD) diffusion. A controlled porous structure containing mesopores (3.8 nm) with micropores (1.8 and 0.87 nm) allowed the “pore filling effect” mechanism and strongly favorable kinetics. A highly oxygenated carbon material (C: 81.84 % O: 15.04 % Si: 1.72 % Na: 1.29 %) with efficient template removal was obtained. Unusual behavior of the rate-limiting step (AAS or IHD) as a function of CIP concentrations was observed, with mechanism changes due to self-aggregation of CIP molecules (dimers, trimers and tetramers).
期刊介绍:
Chemical engineering enables the transformation of natural resources and energy into useful products for society. It draws on and applies natural sciences, mathematics and economics, and has developed fundamental engineering science that underpins the discipline.
Chemical Engineering Science (CES) has been publishing papers on the fundamentals of chemical engineering since 1951. CES is the platform where the most significant advances in the discipline have ever since been published. Chemical Engineering Science has accompanied and sustained chemical engineering through its development into the vibrant and broad scientific discipline it is today.