Treatment of the Thermal Nonequilibrium and Ionization Effects on the Refractive Index of a Reacting Gas: Atmospheric Air and Combustion Products

IF 1 4区 工程技术 Q4 MECHANICS Fluid Dynamics Pub Date : 2024-11-07 DOI:10.1134/S0015462824602614
B. I. Loukhovitski, I. N. Kadochnikov, I. V. Arsentiev, A. S. Sharipov
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Abstract

Using thermal nonequilibrium physicochemical kinetics models, which make it possible to numerically study the reacting gas flows with allowance for the processes of vibrational and electronic-translational relaxation and exchange, as well as the chemical and plasmachemical reactions, the profiles of the Gladstone–Dale constant and refractive index are calculated for two model problems: relaxation of the air behind the shock wave (SW) front and expansion of hydrogen and syngas combustion products in a supersonic nozzle. The required data on the electrical properties (polarizability and dipole moment) of the neutral and charged gas components in their ground and excited states are taken from the literature or estimated using recently developed analytical models. For each of the model gas-dynamic problems, the accuracy of various approximations when calculating the optical properties of a gas is analyzed.

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处理热非平衡和电离对反应气体折射率的影响:大气空气和燃烧产物
热非平衡态物理化学动力学模型可以对反应气体流进行数值研究,同时考虑到振动和电子转换弛豫和交换过程,以及化学和等离子化学反应,利用这些模型计算了两个模型问题的格拉德斯通-戴尔常数和折射率曲线:冲击波(SW)前沿后的空气弛豫以及超音速喷嘴中氢气和合成气燃烧产物的膨胀。所需的中性和带电气体成分在基态和激发态的电特性(极化率和偶极矩)数据来自文献,或使用最近开发的分析模型进行估算。针对每个模型气体动力问题,分析了计算气体光学特性时各种近似值的准确性。
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来源期刊
Fluid Dynamics
Fluid Dynamics MECHANICS-PHYSICS, FLUIDS & PLASMAS
CiteScore
1.30
自引率
22.20%
发文量
61
审稿时长
6-12 weeks
期刊介绍: Fluid Dynamics is an international peer reviewed journal that publishes theoretical, computational, and experimental research on aeromechanics, hydrodynamics, plasma dynamics, underground hydrodynamics, and biomechanics of continuous media. Special attention is given to new trends developing at the leading edge of science, such as theory and application of multi-phase flows, chemically reactive flows, liquid and gas flows in electromagnetic fields, new hydrodynamical methods of increasing oil output, new approaches to the description of turbulent flows, etc.
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Development of the Deposit Formation Similarity Criterion with the Electrochemical Number Direct Statistical Modeling of Oxygen Radiation behind a Shock Wave Treatment of the Thermal Nonequilibrium and Ionization Effects on the Refractive Index of a Reacting Gas: Atmospheric Air and Combustion Products Formation of Three-Phase Cavitation Bubbles with Their Own Electric Field in a Hydrophobic Liquid Numerical Simulation of Vapor Bulk Condensation near the Interfacial Surface under Intensive Evaporation Conditions
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