Optimization of the Synthesis of Salts [V10O28]6– for the Preparation of [VO2(DMSO)4](CF3SO3) and Its Immobilization on Polyethylene Terephthalate for Catalytic Applications
P. A. Abramov, N. B. Kompan’kov, V. S. Sulyaeva, M. N. Sokolov
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引用次数: 0
Abstract
Aspects of the synthesis and isolation of (Bu4N)3[H3V10O28] (I) and Na6[V10O28]·18H2O (II) from one reaction mixture are considered. The procedure for the synthesis of compound I is optimized. The reaction of compound I and HSO3CF3 in dimethyl sulfoxide (DMSO) affords complex [VO2(DMSO)4](CF3-SO3) (III). A possibility of using complex III for the preparation of catalytically active materials based on polyethylene terephthalate (PET) is shown.
本文探讨了从一种反应混合物中合成和分离 (Bu4N)3[H3V10O28] (I) 和 Na6[V10O28]-18H2O (II) 的各方面问题。对化合物 I 的合成过程进行了优化。化合物 I 和 HSO3CF3 在二甲基亚砜（DMSO）中反应生成络合物 [VO2(DMSO)4](CF3-SO3)（III）。图中显示了利用复合物 III 制备基于聚对苯二甲酸乙二醇酯 (PET) 的催化活性材料的可能性。
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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