A. Y. Kapran, Y. I. Pyatnitsky, V. I. Chedryk, S. M. Orlyk
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Abstract
The thermodynamic and kinetic aspects of vapor-phase carbonylation of methanol are considered, in particular the effect of temperature on the equilibrium yield of products and probable routes of acetyls production. The influence of the catalyst composition on the course of the target process, the influence of hydrogen as a gas promoter on the selectivity/yield of acetyls, the peculiarities of the course of the tandem process (coupling of decomposition and carbonylation of methanol) are analyzed.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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