Enhanced removal of cationic dye DRMD using cellulose-graphene oxide composite: kinetics, mechanism and optimization

IF 3 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Adsorption Pub Date : 2024-09-21 DOI:10.1007/s10450-024-00538-8
Joyanta Palit, Sadit Bihongo Malitha, Md. Abu Sayid Mia, Md. Zahangir Alam
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Abstract

Millions of tons of dyes are released into water bodies each year, most of which are azo dyes and pose a threat to soil and water ecosystems. This article introduces a simple sol–gel technique for producing a composite of Cellulose-Graphene oxide (CGO) beads as an adsorbent with outstanding adsorption efficiency for a commercial textile dye, Doracryl Red MD (DRMD). The crystal phases, functional groups, thermal stability, and morphology of GO, Cellulose, and CGO beads were extensively studied using various characterization methods, including XRD, FTIR, FESEM, and TGA. The adsorption process was optimized for different pH levels, dosages, initial dye concentrations, and contact times. The adsorption process followed Freundlich adsorption isotherm and Pseudo-second-order kinetics. CGO adsorbent demonstrated a maximum adsorption capacity of 577.874 mg/g, indicating its potential for eliminating organic contaminants from wastewater.

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利用纤维素-氧化石墨烯复合材料提高阳离子染料 DRMD 的去除率:动力学、机理与优化
每年有数百万吨的染料被排放到水体中,其中大部分是偶氮染料,对土壤和水体生态系统构成威胁。本文介绍了一种简单的溶胶-凝胶技术,用于生产纤维素-氧化石墨烯(CGO)珠的复合吸附剂,对商用纺织染料 Doracryl Red MD(DRMD)具有出色的吸附效率。利用 XRD、FTIR、FESEM 和 TGA 等各种表征方法对 GO、纤维素和 CGO 珠的晶相、官能团、热稳定性和形态进行了广泛研究。针对不同的 pH 值、用量、初始染料浓度和接触时间,对吸附过程进行了优化。吸附过程遵循 Freundlich 吸附等温线和伪秒阶动力学。CGO 吸附剂的最大吸附容量为 577.874 毫克/克,这表明它具有消除废水中有机污染物的潜力。
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来源期刊
Adsorption
Adsorption 工程技术-工程:化工
CiteScore
8.10
自引率
3.00%
发文量
18
审稿时长
2.4 months
期刊介绍: The journal Adsorption provides authoritative information on adsorption and allied fields to scientists, engineers, and technologists throughout the world. The information takes the form of peer-reviewed articles, R&D notes, topical review papers, tutorial papers, book reviews, meeting announcements, and news. Coverage includes fundamental and practical aspects of adsorption: mathematics, thermodynamics, chemistry, and physics, as well as processes, applications, models engineering, and equipment design. Among the topics are Adsorbents: new materials, new synthesis techniques, characterization of structure and properties, and applications; Equilibria: novel theories or semi-empirical models, experimental data, and new measurement methods; Kinetics: new models, experimental data, and measurement methods. Processes: chemical, biochemical, environmental, and other applications, purification or bulk separation, fixed bed or moving bed systems, simulations, experiments, and design procedures.
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