{"title":"Correction to “Steric and Electronic Influence of Excited-State Decay in Cu(I) MLCT Chromophores”","authors":"Felix N. Castellano, Michael C. Rosko","doi":"10.1021/acs.accounts.4c00720","DOIUrl":null,"url":null,"abstract":"The slope presented in Figure 11 illustrates a compelling linear correlation over an emission energy range of ∼0.4 eV (∼3200 cm<sup>–1</sup>) having a slope of −11.3 natural log units/eV, illustrating that energy gap considerations majorly influence excited state decay in this class of chromophores in the absence of donor solvent interactions, regardless of alkyl substitution pattern.<img alt=\"\" src=\"/cms/10.1021/acs.accounts.4c00720/asset/images/medium/ar4c00720_0001.gif\"/> This article has not yet been cited by other publications.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.accounts.4c00720","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The slope presented in Figure 11 illustrates a compelling linear correlation over an emission energy range of ∼0.4 eV (∼3200 cm–1) having a slope of −11.3 natural log units/eV, illustrating that energy gap considerations majorly influence excited state decay in this class of chromophores in the absence of donor solvent interactions, regardless of alkyl substitution pattern. This article has not yet been cited by other publications.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
This article has not yet been cited by other publications.
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