Comparing basal and prismatic slips induced by thermal stresses in 4H-SiC crystals

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY CrystEngComm Pub Date : 2024-10-11 DOI:10.1039/D4CE00927D
Sheng'ou Lu, Binjie Xu, Lingling Xuan, Xiaodong Pi, Deren Yang and Xuefeng Han
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Abstract

Basal and prismatic slips induced by thermoelastic stresses during the growth of 4H-SiC are investigated by using the finite element method (FEM) and considering factors such as the crystal diameter, temperature, and off-axis angle. It is found that with the increase of the crystal diameter from 6 to 8 inches, the prismatic slip more likely occurs, leading to a higher density of basal plane dislocations (BPDs). However, the basal slip hardly changes. The temperature difference, rather than the growth temperature, is the primary factor contributing to the increase in the slip stresses. The stresses of the basal slip are significantly affected by a small off-axis angle, whereas those of the prismatic slip are not unaffected until the off-axis angle reaches 30 degrees. The mechanism for the decrease of the density of BPDs along the growth direction in an 8 inch 4H-SiC crystal is elucidated. We verify that the prismatic slip in an 8 inch 4H-SiC crystal contributes more to the BPD formation than the basal slip.

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比较热应力在 4H-SiC 晶体中诱发的基底滑移和棱柱滑移
通过使用有限元法(FEM)并考虑晶体直径、温度和离轴角等因素,研究了 4H-SiC 生长过程中由热弹性应力引起的基底位错和棱柱位错。研究发现,随着晶体直径从 6 英寸增大到 8 英寸,棱柱滑移更有可能发生,从而导致基底面位错(BPDs)密度增大。然而,基面滑移几乎没有变化。温差而非生长温度是导致滑移应力增加的主要因素。基底滑移的应力受小偏轴角的影响很大,而棱柱滑移的应力在偏轴角达到 30 度之前并非不受影响。我们阐明了 8 英寸 4H-SiC 晶体中 BPD 密度沿生长方向降低的机理。我们验证了在 8 英寸 4H-SiC 晶体中棱柱滑移比基底滑移对 BPD 形成的影响更大。
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来源期刊
CrystEngComm
CrystEngComm 化学-化学综合
CiteScore
5.50
自引率
9.70%
发文量
747
审稿时长
1.7 months
期刊介绍: Design and understanding of solid-state and crystalline materials
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