{"title":"Structural transformation of silver(i)–thiolate coordination polymer film at solid–liquid interfaces†","authors":"Myu Fukuoka, Yohei Takashima, Kensuke Akamatsu, Aude Demessence and Takaaki Tsuruoka","doi":"10.1039/D4CE01023J","DOIUrl":null,"url":null,"abstract":"<p >We report that the ligand-exchange reaction between [Ag(<em>o</em>-SPhCO<small><sub>2</sub></small>H)]<small><sub><em>n</em></sub></small> deposited on a solid substrate and the free <em>p</em>-HSPhCOOH ligand in solution results in crystal transformation from [Ag(<em>o</em>-SPhCO<small><sub>2</sub></small>H)]<small><sub><em>n</em></sub></small> to [Ag(<em>p</em>-SPhCO<small><sub>2</sub></small>H)]<small><sub><em>n</em></sub></small> on the substrate. Structural analysis revealed a structural transformation between CPs with different topologies <em>via</em> ligand exchange.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 44","pages":" 6269-6273"},"PeriodicalIF":2.6000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ce/d4ce01023j?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce01023j","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
We report that the ligand-exchange reaction between [Ag(o-SPhCO2H)]n deposited on a solid substrate and the free p-HSPhCOOH ligand in solution results in crystal transformation from [Ag(o-SPhCO2H)]n to [Ag(p-SPhCO2H)]n on the substrate. Structural analysis revealed a structural transformation between CPs with different topologies via ligand exchange.
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