{"title":"Scaling up clean production of biomass-derived organic acids as a step towards the realization of dual carbon goals: a review","authors":"Zulfiqar Ali, Jiliang Ma and Runcang Sun","doi":"10.1039/D4GC03829K","DOIUrl":null,"url":null,"abstract":"<p >The contemporary world faces issues related to energy, the environment, and food security. The use of carbon capture, storage, and utilization technologies can help reduce CO<small><sub>2</sub></small> emissions from fossil fuels, which will result in major advancements toward dual carbon targets. In addition to promoting environmentally friendly manufacturing, chemical industries may replace fossil fuel-based raw materials with renewable biomass for the synthesis of organic acids and syngas. Although several studies are being conducted on co-valorization of CO<small><sub>2</sub></small> and biomass feedstocks to produce organic acids and fine chemicals using biotechnology, thermocatalysis, electrocatalysis, and photocatalysis, there are still various obstacles in scaling up clean production, including (i) addressing environmental concerns, (ii) the intricate structure and chemical composition of biomass, (iii) conversion mechanisms and processes, (iv) designing catalyst materials with higher durability and recyclability, (v) greener solvent systems for catalysis and extraction, (vi) the deployment of modern technologies for characterization, (vii) training and guidelines for industrial operations, and (viii) governmental financing and policy. The sustainable manufacturing of biobased products from raw feedstocks produced from biomass has been made possible <em>via</em> technological breakthroughs in photo-/biorefineries, which are essential for the clean and environmentally friendly synthesis of organic acids. It is anticipated that clean production of organic acids from biomass will have a dominant market share, benefiting from both socioeconomic and environmental factors. With future technical developments, the valorization of feedstocks obtained from biomass together with CO<small><sub>2</sub></small> for manufacturing fuels and fine chemicals will be more ecologically and economically feasible.</p>","PeriodicalId":9,"journal":{"name":"ACS Catalysis ","volume":null,"pages":null},"PeriodicalIF":11.3000,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Catalysis ","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/gc/d4gc03829k","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The contemporary world faces issues related to energy, the environment, and food security. The use of carbon capture, storage, and utilization technologies can help reduce CO2 emissions from fossil fuels, which will result in major advancements toward dual carbon targets. In addition to promoting environmentally friendly manufacturing, chemical industries may replace fossil fuel-based raw materials with renewable biomass for the synthesis of organic acids and syngas. Although several studies are being conducted on co-valorization of CO2 and biomass feedstocks to produce organic acids and fine chemicals using biotechnology, thermocatalysis, electrocatalysis, and photocatalysis, there are still various obstacles in scaling up clean production, including (i) addressing environmental concerns, (ii) the intricate structure and chemical composition of biomass, (iii) conversion mechanisms and processes, (iv) designing catalyst materials with higher durability and recyclability, (v) greener solvent systems for catalysis and extraction, (vi) the deployment of modern technologies for characterization, (vii) training and guidelines for industrial operations, and (viii) governmental financing and policy. The sustainable manufacturing of biobased products from raw feedstocks produced from biomass has been made possible via technological breakthroughs in photo-/biorefineries, which are essential for the clean and environmentally friendly synthesis of organic acids. It is anticipated that clean production of organic acids from biomass will have a dominant market share, benefiting from both socioeconomic and environmental factors. With future technical developments, the valorization of feedstocks obtained from biomass together with CO2 for manufacturing fuels and fine chemicals will be more ecologically and economically feasible.
期刊介绍:
ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels.
The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.