Synthesis and Crystal Structure of the First Aqueous Silver Borate Nitrate Ag3B4O6(OH)2(NO3)

IF 1.2 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Journal of Structural Chemistry Pub Date : 2024-11-11 DOI:10.1134/S0022476624100019

Y. O. Kopylova, S. N. Volkov, S. M. Aksenov, R. S. Bubnova

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Abstract

The first aqueous silver borate nitrate Ag₃B₄O₆(OH)₂(NO₃) has a non-centrosymmetric crystal structure (P4₃2₁2, a = 10.0196(3) Å, c = 9.2594(2) Å). The compound is prepared by soft hydrothermal synthesis inside an evacuated quartz ampoule. The structure of the resulting 1D–5B-borate compound is formed by [B₄O₆(OH)₂]^2– chains consisting of two triborate rings with a common (2Δ3□:(‹Δ2□›–‹Δ2□›–)^∞ tetrahedron and NO₃ triangles with silver atoms between the rings. The relationship between the structures of Ag₃B₄O₆(OH)₂(NO₃), Tl₂B₄O₆(OH)₂·2H₂O and the kernite Na₂B₄O₆(OH)₂·3H₂O (also formed by [B₄O₆ (OH)₂]^2– chains) is discussed.

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第一种硝酸银硼酸盐水溶液 Ag3B4O6(OH)2(NO3) 的合成与晶体结构

第一种含水硼酸银硝酸盐 Ag3B4O6(OH)2(NO3) 具有非中心对称晶体结构 (P43212, a = 10.0196(3) Å, c = 9.2594(2) Å)。该化合物是在一个抽真空的石英安瓿瓶中通过软水热合成制备的。得到的 1D-5B 硼酸盐化合物的结构是由[B4O6(OH)2]2-链构成的，该链由两个三硼酸盐环组成，环之间有一个共同的（2Δ3□:('Δ2□'-'Δ2□'-)∞四面体和带有银原子的 NO3 三角形。讨论了 Ag3B4O6(OH)2(NO3)、Tl2B4O6(OH)2-2H2O 和赤铁矿 Na2B4O6(OH)2-3H2O（也由 [B4O6 (OH)2]2- 链形成）结构之间的关系。

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来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.