Use of Organo-Inorganic Binder in the Composition of Mineral Wool Products

IF 0.4 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS Refractories and Industrial Ceramics Pub Date : 2024-10-19 DOI:10.1007/s11148-024-00893-7
V. I. Matyukhin, V. A. Ulomskii, A. V. Matyukhina
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Abstract

The main purpose of a liquid binder in the composition of mineral wool products is to bond individual fibers to each other to create a strong and elastic structure. The combined use of an organic (phenol-formaldehyde resin) and an inorganic binder based on cold dissolution liquid glass is accompanied during their mechanical mixing by the formation of complex carbon-silicon compounds, which stabilize the formation of chelate compounds with an orienting effect of silicon ion during heat treatment, converting the polymer structure to a more ordered and dense structure with additional bridging hydrogen bonds. This process is accompanied by the parallel development of a polycondensation reaction of the organic binder and methylol groups and curing of the liquid glass. The presence of intramolecular bonds between the organic and inorganic parts of the binder increases the bond strength of the mineral fibers when forming the structure of fibrous thermal insulation materials by 20 – 30% with a slight increase in their water absorption. Limited use of cold dissolution liquid glass additives (not more than 0.4%) allows a reduction in the total consumption of organic binder by 20 – 25% with the possibility of reducing the required amount of mineral part by up to 10 – 15% while maintaining the required strength and operational properties of finished heat-insulating products.

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在矿棉产品成分中使用有机-无机粘合剂
在矿棉产品的成分中使用液体粘结剂的主要目的是将单根纤维相互粘结在一起,以形成坚固而有弹性的结构。有机粘合剂(酚醛树脂)和基于冷溶解液态玻璃的无机粘合剂在机械混合过程中会形成复杂的碳硅化合物,这些化合物在热处理过程中会稳定形成具有硅离子定向效应的螯合物,从而将聚合物结构转化为更有序、更致密的结构,并带有额外的桥接氢键。在这一过程中,有机粘合剂和甲醇基团同时发生缩聚反应,并固化成液态玻璃。在形成纤维状隔热材料结构时,粘合剂的有机部分和无机部分之间存在的分子内键使矿物纤维的粘合强度提高了 20-30%,同时吸水性也略有增加。有限度地使用冷溶解液态玻璃添加剂(不超过 0.4%)可将有机粘合剂的总用量减少 20-25%,同时可将矿物部分的所需用量最多减少 10-15%,并保持隔热成品所需的强度和操作性能。
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来源期刊
Refractories and Industrial Ceramics
Refractories and Industrial Ceramics 工程技术-材料科学:硅酸盐
CiteScore
0.90
自引率
20.00%
发文量
38
审稿时长
6-12 weeks
期刊介绍: Refractories and Industrial Ceramics publishes peer-reviewed articles on the latest developments and discoveries in the field of refractory materials and ceramics, focusing on the practical aspects of their production and use. Topics covered include: Scientific Research; Raw Materials; Production; Equipment; Heat Engineering; Applications.
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