{"title":"Ortho-allylation of anilines with vinylaziridines in hexafluoroisopropanol","authors":"Jing-Jing Nie, Zhong-Xia Wang","doi":"10.1039/d4qo01719f","DOIUrl":null,"url":null,"abstract":"Transition-metal-free reaction of N,N-dialkylanilines with 1-sulfonyl-2-vinylaziridines in hexafluoroisopropanol in air gave ortho-allylated anilines in moderate to excellent yields. The reaction also features mild reaction conditions, ortho-monoallylation selectivity, E-configurated C-C double bonds, wide substrate scope and good compatibility of functional groups.","PeriodicalId":97,"journal":{"name":"Organic Chemistry Frontiers","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4qo01719f","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
Transition-metal-free reaction of N,N-dialkylanilines with 1-sulfonyl-2-vinylaziridines in hexafluoroisopropanol in air gave ortho-allylated anilines in moderate to excellent yields. The reaction also features mild reaction conditions, ortho-monoallylation selectivity, E-configurated C-C double bonds, wide substrate scope and good compatibility of functional groups.
期刊介绍：
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.
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