{"title":"ortho-Allylation of anilines with vinylaziridines in hexafluoroisopropanol†","authors":"Jing-Jing Nie , Zhong-Xia Wang","doi":"10.1039/d4qo01719f","DOIUrl":null,"url":null,"abstract":"<div><div>Transition-metal-free reaction of <em>N</em>,<em>N</em>-dialkylanilines with 1-sulfonyl-2-vinylaziridines in hexafluoroisopropanol under air gave <em>ortho</em>-allylated anilines in moderate to excellent yields. The reaction also features mild reaction conditions, <em>ortho</em>-monoallylation selectivity, <em>E</em>-configured C–C double bonds, wide substrate scope and good compatibility of functional groups.</div></div>","PeriodicalId":94379,"journal":{"name":"Organic chemistry frontiers : an international journal of organic chemistry","volume":"12 2","pages":"Pages 629-635"},"PeriodicalIF":0.0000,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic chemistry frontiers : an international journal of organic chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2052412924008088","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/14 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Transition-metal-free reaction of N,N-dialkylanilines with 1-sulfonyl-2-vinylaziridines in hexafluoroisopropanol under air gave ortho-allylated anilines in moderate to excellent yields. The reaction also features mild reaction conditions, ortho-monoallylation selectivity, E-configured C–C double bonds, wide substrate scope and good compatibility of functional groups.
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