Cold sintering of nickel manganese oxide for thermistor fabrication

IF 9.5 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Journal of Materials Chemistry A Pub Date : 2024-11-14 DOI:10.1039/D4TA06380E
Julian Fanghanel, Satoshi Yokomizo, Shuichi Funahashi and Clive A. Randall
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Abstract

In this paper we successfully densified NiMn2O4 (NMO) ceramics using the cold sintering process (CSP) with various molten salt fluxes as a transient liquid phase, achieving relative densities exceeding 95%. The resulting samples exhibited comparable properties to conventionally sintered counterparts, demonstrating the feasibility of the CSP for NMO thermistor production. Electrical characterization revealed NMO samples sintered via CSP exhibited negative temperature coefficient (NTC) behavior with material constants (B) and temperature coefficients of resistivity (α) akin to conventionally sintered materials in the range of 3500–4300 K and 0.04–0.05 K−1. Despite slightly higher resistances attributed to differences in grain size and impurities, the CSP-produced NMO samples remained within the typical range for NTC thermistors.

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冷烧结镍锰氧化物制造热敏电阻器
在本文中,我们采用冷烧结工艺(CSP),以各种熔盐流量作为瞬态液相,成功地对镍锰氧化物(NMO)陶瓷进行了致密化处理,使其相对密度超过 95%。所得样品的性能与传统烧结样品相当,证明了 CSP 用于 NMO 热敏电阻生产的可行性。电学特性分析表明,通过 CSP 烧结的 NMO 样品表现出 NTC 行为,其材料常数 (β) 和电阻率温度系数 (α)与传统烧结材料类似,范围分别为 3500-4300 K 和 0.04-0.05 K-1。尽管由于晶粒尺寸和杂质的不同而导致电阻率略高,但 CSP 生产的 NMO 样品仍在 NTC 热敏电阻的典型范围内。
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来源期刊
Journal of Materials Chemistry A
Journal of Materials Chemistry A CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
19.50
自引率
5.00%
发文量
1892
审稿时长
1.5 months
期刊介绍: The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.
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