V. V. Semenov, N. V. Zolotareva, N. M. Lazarev, B. I. Petrov, T. I. Lopatina, E. N. Razov
{"title":"Crystal Morphology of Triethylenediaminium and Tetramethylethylenediaminium Ethylenediaminetetraacetatozincates","authors":"V. V. Semenov, N. V. Zolotareva, N. M. Lazarev, B. I. Petrov, T. I. Lopatina, E. N. Razov","doi":"10.1134/S1063774523601491","DOIUrl":null,"url":null,"abstract":"<p>Triethylenediaminium ethylenediaminetetraacetatozincate trihydrate ([HN(CH<sub>2</sub>CH<sub>2</sub>)<sub>3</sub>NH]Zn<i>L</i>⋅ 3H<sub>2</sub>О) and tetramethylethylenediaminium ethylenediaminetetraacetatozincate dihydrate ([H(CH<sub>3</sub>)<sub>2</sub>NCH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)<sub>2</sub>H]Zn<i>L</i>⋅2H<sub>2</sub>О) were synthesized by the reaction of zinc oxides with ethylenediaminetetraacetic acid and then with its triethylenediaminum or tetramethylethylenediaminium salts. The synthesized compounds were isolated from aqueous solutions or organic solvents as fiber-like, cubic, and pyramidal crystals, which were characterized by elemental analysis, scanning electron microscopy, IR spectroscopy, thermogravimetry, and differential scanning calorimetry.</p>","PeriodicalId":527,"journal":{"name":"Crystallography Reports","volume":"69 5","pages":"668 - 673"},"PeriodicalIF":0.6000,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystallography Reports","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S1063774523601491","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0
Abstract
Triethylenediaminium ethylenediaminetetraacetatozincate trihydrate ([HN(CH2CH2)3NH]ZnL⋅ 3H2О) and tetramethylethylenediaminium ethylenediaminetetraacetatozincate dihydrate ([H(CH3)2NCH2CH2N(CH3)2H]ZnL⋅2H2О) were synthesized by the reaction of zinc oxides with ethylenediaminetetraacetic acid and then with its triethylenediaminum or tetramethylethylenediaminium salts. The synthesized compounds were isolated from aqueous solutions or organic solvents as fiber-like, cubic, and pyramidal crystals, which were characterized by elemental analysis, scanning electron microscopy, IR spectroscopy, thermogravimetry, and differential scanning calorimetry.
期刊介绍：
Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.
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