Isobaric Specific Heat Capacity Measurement in the Trans-Critical Temperature Regions for Kerosene RP-3 under Pressures of 6–8 MPa

IF 2.1 3区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Chemical & Engineering Data Pub Date : 2024-10-10 DOI:10.1021/acs.jced.4c00181
Yanchen Fu, Xiaojia Gang, Haoxing Zhi, Yinlong Liu and Guoqiang Xu*, 
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Abstract

A new experimental method was proposed: the enthalpy difference method to measure the isobaric specific heat capacity of RP-3 at 6–8 MPa, 338.1–788.3 K. According to the calculation of the uncertainty of the relevant experimental apparatus, compared with the normal measurement method, the enthalpy difference method can reduce the uncertainty from 5.17 to 3.65%. The results were verified by using n-decane. The results showed that compared with National Institute of Standards and Technology (NIST), the average error of the experimental results of n-decane was 1.8%. Experimental results show that the measured peak isobaric specific heat capacity of RP-3 in this range is 3.93 kJ/kg (slightly less than the true value of the substance). As the pressure increases, its peak value gradually decreases until it becomes flat.

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6-8 兆帕压力下煤油 RP-3 跨临界温度区域的等压比热容测量结果
根据对相关实验仪器不确定度的计算,与普通测量方法相比,焓差法可将不确定度从 5.17% 降低到 3.65%。使用正癸烷对结果进行了验证。结果表明,与美国国家标准与技术研究院(NIST)相比,正癸烷实验结果的平均误差为 1.8%。实验结果表明,在此范围内测得的 RP-3 等压比热容峰值为 3.93 kJ/kg(略低于物质的真实值)。随着压力的增加,其峰值逐渐减小,直至持平。
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来源期刊
Journal of Chemical & Engineering Data
Journal of Chemical & Engineering Data 工程技术-工程:化工
CiteScore
5.20
自引率
19.20%
发文量
324
审稿时长
2.2 months
期刊介绍: The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.
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